摘要
环三磷腈及其衍生物是一类以磷-氮单双键为基本骨架,具有不同功能性侧基的化合物。随着科技的进步和发展,它被广泛应用于生活中的各个领域,例如阻燃、生物医药、光电材料等方面。本文以六氯环三磷腈(HCCP)、邻氨基苯酚为原料,三乙胺作缚酸剂,四氢呋喃作溶剂,采用一锅法,经过亲核取代反应生成一种新型环三磷腈化合物——三(邻氨基苯氧基)环磷腈,经红外光谱(IR)、磁核共振(NMR)表征,并对合成条件进行了研究与优化。
The cyclotriphosphazene and its relative derivatives are a class of compounds which with phosphorus-nitrogen single and double bonds as a basic skeleton and different functional side groups,with the advancement and development of technology. It is widely used in all areas of our life, such as flame retardant, biomedical, optical materials, ect.In this paper, hexachlorocyclot- riphos-phazene （HCCP） and o-aminophenol as starting materials,triethylamine as acid-binding agent,tetrahydrofuran as a sol- vent,the one-pot method, after nuclepphilic substitution reaction to synthesize a novel compound cyclotriphosphazene-Tris （phenylene-l-amino-2-oxy） tricycloph-osphazene via infrared spectroscopy（IR） and unclear magnetic resonance（NMR） charac-terization of the structure, synthesis and condition were studied and optimized.
出处
《衡阳师范学院学报》
2016年第6期60-63,共4页
Journal of Hengyang Normal University
基金
湖南省教育厅科学研究项目(16C0224)
衡阳市工业科技支撑计划项目(2014KG85)
衡阳师范学院院级青年项目(13A20)
关键词
环三磷腈
邻氨基苯酚
三(邻氨基苯氧基)环磷腈
合成
阻燃剂
cyclotriphosphazene
O-aminophenol
tris（phenylene-1-amino-2-oxy） tricyclo-phosphazene
synthesis
flame re- tardant
