摘要
The organic light-emitting devices(OLEDs) using 4,4',4''-tris{N-(3-methylphenyl)-N-phenylamin}triphenylamine(m-MTDATA) and MoO_3 or 1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride(TAPC) and MoO_3 as the hole-injection layer(HIL) were fabricated. MoO_3 can be expected to be a good injection layer material and thus enhance the emission performance of OLED. The highest occupied molecular(HOMO) of MoO_3 is between those of m-MTDATA or TAPC and N,N'-bis-(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine(NPB),which reduces the hole-injection barrier and improves the luminance of the OLEDs. The current efficiency is improved compared with that of the device without the MoO_3 layer. The highest luminous efficiency of the device with 2-nm-thick MoO_3 as HIL is achieved as 5.27 cd/A at 10 V,which is nearly 1.2 times larger than that of the device without it. Moreover,the highest current efficiency and power efficiency of the device with the structure indium-tin oxide(ITO)/TAPC(40 nm)/MoO_3(2 nm)/Tc Ta:Ir(ppy)3(10%,10 nm)/ tris-(8-hydroxyquinoline) aluminium(Alq)(60 nm)/Li F(1 nm)/Al are achieved as 37.15 cd/A and 41.23 lm/W at 3.2 V and 2.8 V,respectively.
作者
YANG Hui-shan
WU Li-shuang
杨惠山;吴丽双(College of Physics and Information Engineering, Quanzhou Normal University, Quanzhou 362000, China)
基金
supported by the Major Project of Science and Technology Office of Fujian Province of China(No.2014H0042)
the Natural Science Foundation of Fujian Province of China(No.2015J01664)
the Project of Science and Technology Research of Quanzhou City in Fujian Province of China(Nos.2013Z125 and 2014Z137)
