摘要
Two new rearranged diterpenoids, tomocinol C (1) and spirocaesalmin C (2) were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data, and their absolute configurations were established by single crystal X-ray crystallography.
Two new rearranged diterpenoids, tomocinol C (1) and spirocaesalmin C (2) were isolated from the seeds of Caesalpinia sappan. Their structures were elucidated based on comprehensive analysis of spectroscopic data, and their absolute configurations were established by single crystal X-ray crystallography.
基金
financial support of the National Science & Technology Major Project ‘‘Key New Drug Creation and Manufacturing Program’’ (No.2012ZX09301001-001)
the National Natural Science Funds (No.81302657,81473112,81573305)
the Chinese Academy of Sciences (No.KSZD-EW-Z-004-01)
the Shanghai Commission of Science and Technology (No.12JC1410300)