摘要
以碘代芳烃与芳基硼酸在钯催化下的Suzuki交叉偶合反应为关键步骤,采用收敛法成功合成了一系列结构不对称的含噁二唑π-共轭寡聚芳烃OX-Ph3An,OX-Ph3Np和OX-Ph3TPA,并对它们的结构、热学性质、光学性质和电化学性质进行了表征。结果表明：新合成的不对称含噁二唑π-共轭寡聚芳烃具有很高的热稳定性（Tdec=487-517℃）和较高的玻璃态转化温度（Tg=91-112℃）。
A series of unsymmetrically oxadiazole-based π-conjugated oligoarylenes,OX-Ph3An,OX-Ph3Np and OX-Ph3TPA had successfully been synthesized by a divergent approach using Pd-catalyzed Suzuki cross-coupling reaction of iodo-oligoarylene and arylboronic acid as a key step.Their optical,electro-chemical and thermal properties had also been characterized. These novel synthesized oxadiazole-based oligoarylenes showed highly glass transition temperatures（ Tg= 91 - 112℃） and thermal stabilities（ Tdec=487 - 517℃）.
作者
邓国伟
张琦
奉强
何冰
刘玉容
韩涛
孙康
张小玲
李仲辉
DENG Guo-wei ZHANG Qi FENG Qiang HE Bing LIU Yu-rong HAN Tao SUN Kang ZHANG Xiao-ling LI Zhong-hui(Institute of Functional Molecules,Chengdu Normal University,Chengdu 611130,China College of Chemistry and Biology,Chengdu Normal University,Chengdu 611130,China)
出处
《化学研究与应用》
CAS
CSCD
北大核心
2016年第11期1556-1562,共7页
Chemical Research and Application
基金
四川省科学技术厅科技支撑计划项目(2009GZ0167
2012FZ0129)资助
关键词
噁二唑
寡聚芳烃
合成
性质
oxadiazole
oligoarylene
synthesis
property
