摘要
以延安某污水处理厂剩余污泥为原料,采用氢氧化钾活化法制备了花生壳基污泥活性炭,在对其进行性能表征的基础上,研究了吸附动力学过程。通过正交实验确定了花生壳基污泥活性炭的最佳制备条件为碳化温度350℃、碳化时间40min、氢氧化钾摩尔浓度0.5mol/L、花生壳添加比例(质量分数)20%。通过比表面积、傅立叶红外光谱、扫描电子显微镜、能谱分析发现,花生壳基污泥活性炭表面粗糙,呈多孔结构,比表面积为226.39m^2/g,平均孔径为5.170nm,C元素质量分数为67.52%,出现了酚羟基、醚键、内酯键等基团。当花生壳基污泥活性炭投加量为2.0g/L时,处理含油量为120 mg/L的含油废水,油类污染物去除率可达94%,其吸附过程符合伪二级动力学方程。
The municipal sewage sludge from a sewage treatment plant in Yan＇an was used to prepare the pea-nut hull sludge-based activated carbon through KOH activation method. The property characterization and the asdorption process were studied. The optimum conditions for the preparation of the peanut hull sludge-based activated carbon by orthogonal experiment were carbonization temperature of 350 °C,carbonization time of 40 min, KOH molar concentration of 0.5 mol/L,and peanut hull mass fraction of 20%. The specific area,Fourier transform infrared spec-troscopy, scanning electron microscope and energy dispersive spectrometer results showed that the surface of peanut hull sludge-based activated carbon was coarse and porous with hydroxy of phenol,ether bond and ester bond appeared; the specific surface area was 226.39 m2/g and the average pore size was 5.170 nm ; the mass fraction of C element was 67.52%. When 2.0 g/L peanut hull sludge-based activated carbon was added,the removal rate of oil achieved 94% for treament of 120 mg/L oily wastewater. The adsorption process was well described by the pseudo second-order kinetic equation.
出处
《环境污染与防治》
CAS
CSCD
北大核心
2016年第9期43-47,共5页
Environmental Pollution & Control
基金
陕西省教育厅科研计划项目(No.15JK185)
陕西省高水平大学专项(No.2013SXTS03)
国家级大学生创新训练计划项目(No.201410719008)
延安大学校级科研青年项目(No.YDQ2014-52)
关键词
花生壳基污泥活性炭
氢氧化钾活化法
含油废水
吸附动力学
peanut hull sludg-based activated carbon
KOH activation method
oily wastewater
adsorption kinetics
