A Simple Determination of Polyethylene Oxide-type Non-ionic Surfactant by Adhesion Method
A Simple Determination of Polyethylene Oxide-type Non-ionic Surfactant by Adhesion Method
摘要
A simple and rapid method for the determination of polyethylene oxide-type non-ionic surfactants is reported herein. This method is based on the adhesion of calcium/non-ionic surfactant complexes with tetra phenyl porphine sulfonic acid （TPPS） to the wall of reaction vessel upon vigorous shaking. The ion-associate adhering to the inner wall of the vessel was dissolved with water after discarding the solution and spectrophotometrically assayed at 412 nm. From the standard curve for Triton X-100, the order of the sensitivity for different ions was as follows： Ca^2＋〉 K^＋〉 NH4^＋〉 Ba^2＋. The proposed method does not involve extraction of the ion-associated with harmful solvents and can be simply performed by combining a procedure based on hand shaking and the use of a spectrophotometer.
作者
Minori Kamaya
Kazuki Nunokawa
Elena Ginatullina
Minori Kamaya;Kazuki Nunokawa;Elena Ginatullina(Department of Applied Chemistry, School of Advanced Engineering, Kogakuin University, Hachioji-City 1920015, Japan;Department of Water and Soil Hygiene, Research Institute of Sanitary and Hygiene, Oltyn-tepa str, 325, Tashkent 100055,Uzbekistan)
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