摘要
探讨了高效液相色谱（DAD检测器）法测定荧光增白剂BA、CXT、BBU,采用Eclipse Plus C18（4.6 mm×100 mm,3.5μm）色谱柱,流动相乙腈-水进行梯度洗脱,检测波长为348 nm。结果表明,BA在5~1 000 mg/L具有良好的线性关系（r=0.999 7）,CXT在1~1 000 mg/L具有良好的线性关系（r=0.999 9）,BBU在50~1 000 mg/L具有良好的线性关系（r=0.999 9）。3种荧光增白剂的RSD值分别为2.82%、1.71%以及1.48%（n=6）。该方法精密度高,重现性好,数据准确可靠。
A new method was investigated to determine three fluorescent whitening agents by liquid chromatography （DAD）. The fluorescent whitening agents were analyzed by Eclipse Plus C18 column （4.6 mm ×100 mm, 3.5 μm）, employing acetonitrile-water as the mobile phase in a gradient elution mode. Meanwhile, the detection wavelength was 348 nm. The results showed that there was good linear relationship in the range of 5-1 000 mg/L for BA （r=0.999 7）; while in the range of 1-1 000 mg/L for CXT （r=0.999 9）. BBU also had good linear relationship in the range of 50-1 000 mg/L （r=0.999 9）. The RSD values of three fluorescent whitening agents were 2.82%, 1.71% and 1.48% （n=6）, respectively. This method was precise and had good reproducibility, accurate and reliable data.
出处
《印染助剂》
CAS
北大核心
2016年第5期58-60,共3页
Textile Auxiliaries
基金
江苏省博士后科研资助计划项目(1302164C)
