摘要
文章以1,4-二(2-吡啶基)甲氧基苯(L)为配体与过渡金属盐Mn Cl2 4 H2O反应制备了配合物[Mn Cl2-L]0.5 H2O,并通过核磁和元素分析对它们进行了结构表征,同时探讨了配合物的催化性能。研究结果表明配合物能够催化过氧化氢氧化降解活性蓝19染料,系统研究了配合物用量、p H、温度等对催化活性的影响,发现配合物[Mn Cl2-L]·0.5 H2O优异的催化脱色性能,在废水处理方面具有广阔的应用前景。
In the paper 1,4-(di-2-pyridyl)methoxy benzene(C_(18)H_(16)O_2N_2)was synthesized, then it was used as the ligand to coordinate with MnCl_2.4H_2O to form corresponded complex[MnCl_2L]0.5 H_2O. The structure was characterized by ~1HNMR and EA. This complex has good catalytic property in degradation of Reactive Blue 19 by H_2O_2. The effects on the catalytic activity such as catalyst dosage, p H and temperature were studied in detail. The results show that [MnCl_2L]0.5 H_2O has good catalytic activity, which have potential application in wastewater treatment.
出处
《广东化工》
CAS
2016年第6期6-7,共2页
Guangdong Chemical Industry