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基于1,4-二(2-吡啶基)甲氧基苯的配合物的制备及其催化过氧化氢降解活性蓝19的性能研究

Synthesis of the Coordination Complexes[MnCl_2-L]0.5H_2O(L,1,4-(Di-2-Pyridyl) Methoxy Benzene) and Its Catalytic Property in Degradation of Reactive Blue 19
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摘要 文章以1,4-二(2-吡啶基)甲氧基苯(L)为配体与过渡金属盐Mn Cl2 4 H2O反应制备了配合物[Mn Cl2-L]0.5 H2O,并通过核磁和元素分析对它们进行了结构表征,同时探讨了配合物的催化性能。研究结果表明配合物能够催化过氧化氢氧化降解活性蓝19染料,系统研究了配合物用量、p H、温度等对催化活性的影响,发现配合物[Mn Cl2-L]·0.5 H2O优异的催化脱色性能,在废水处理方面具有广阔的应用前景。 In the paper 1,4-(di-2-pyridyl)methoxy benzene(C_(18)H_(16)O_2N_2)was synthesized, then it was used as the ligand to coordinate with MnCl_2.4H_2O to form corresponded complex[MnCl_2L]0.5 H_2O. The structure was characterized by ~1HNMR and EA. This complex has good catalytic property in degradation of Reactive Blue 19 by H_2O_2. The effects on the catalytic activity such as catalyst dosage, p H and temperature were studied in detail. The results show that [MnCl_2L]0.5 H_2O has good catalytic activity, which have potential application in wastewater treatment.
出处 《广东化工》 CAS 2016年第6期6-7,共2页 Guangdong Chemical Industry
关键词 1 4-二(2-吡啶基)甲氧基苯 配合物 催化降解 活性蓝19 1 4-(di-2-pyridyl)methoxy benzene complex atalytic degradation reactive blue 19
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