摘要
巯基三氮唑是一种含硫氮杂环有机化合物,由于具有多个配位点和较强的配位能力以及衍生物的多样性,近些年在配位化合物、医药等方面受到广泛研究。本文按照取代基数目的不同将巯基三氮唑衍生物分为疏基三氮唑、单取代巯基三氮唑、多取代巯基三氮唑、多臂巯基三氮唑衍生物,并按照分类系统地总结了近些年来这类配体及其金属配合物的合成方法和结构特征方面的研究成果,同时介绍了其金属配合物在药物、功能材料方面的应用。最后依据巯基三氮唑及其衍生物构筑配合物的研究现状,从配体、金属离子两方面对巯基三氮唑未来的研究方向进行了展望。
Mercaptotriazole is a class of heterocyclic ligands containing sulfur and nitrogen,which gains rapid and extensive studies in both medicine and coordination chemistry, because their derivatives show various properties and these compounds can also coordinate with variety of metal ions to form different complexes. This paper reviewed the advances in the synthesis and structure characterization of mercaptotriazole compounds and their metal complexes. According to the number of substituted groups,four classes mercaptotriazole of mono substituted,disubstituted and multi-arm,were described as well as their applications for drugs and functional materials. Finally,according to the research status of mercaptotriazole and their derivatives,the potential applications of coordination polymers based on mercaptotriazole were discussed from two aspects of ligands and metal ions.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2016年第3期837-846,共10页
Chemical Industry and Engineering Progress
基金
国家自然科学基金青年基金(21201155)
山西省青年基金(2012021007-5
2013021008-6)项目
关键词
配合物
巯基三氮唑
合成
生物技术
功能材料
complexes
mercaptotriazole
synthesis
biotechnology
functional materials
