摘要
利用水热合成法得到了一个结构新颖的砷钼酸盐[Ni(dien)_2])_2[As_6NiMo_6O_(30)]·2H_2O(1)(dien=二乙烯三胺),并用红外光谱、元素分析、热重分析和X射线单晶衍射对之进行了表征.化合物1属于单斜晶系,P2(1)/n空间群.化合物1是由[As_6NiMo_6O_(30)]^(4-)阴离子簇和[Ni(dien)_2]^(2+)配合物构成.
A novel arsenamolybdate[Ni（dien）2]2[As6NiMo6O（30）]·2H2O（1）（dien= diethylenetriamine）,has been prepared by hydrothermal methods and structurally characterized by elemental analysis,IR,TG analysis and single-crystal X-ray diffraction analysis.Compound 1crystallizes in the monoclinic space group P2（1）/n.The structure of 1 is constructed from[As6NiMo6O（30）]4-anionic clusters and[Ni（dien）2]^2＋ complex subunits.
出处
《化学研究》
CAS
2016年第1期57-61,共5页
Chemical Research
基金
The Foundation of Education Department of Henan Province(15A150037)
