摘要
以半连续铸造7136铝合金为研究对象,以铸态组织分析为基础,采用双级均匀化.结果表明:与其他7×××系铝合金相比,7136铝合金铸态组织没有明显的层片状α(Al)+T共晶相的特征,也没有发现S相的存在.基体中的弥散相为微米级的圆形或棒状MgZn2相,Mg元素和Zn元素随着液态合金的凝固,在Al基体中以MgZn2相的形式析出,为了平衡Mg元素和Zn元素的分配系数,Mg元素和Zn元素从液态向固态迁移,这也是使得晶内Zn元素和Mg元素偏高的原因.经过462℃,24 h单级均匀化,残留相大致消除.随着均匀化时间的延长,残留相有减少的趋势,但作用相对较小.经过450℃,24 h+470℃,24 h双级均匀化,差示扫描量热法获取的峰值非常小,晶间除了少量高熔点Al7Cu2Fe相残留,Al2Cu等其他相已基本消除,均匀化效果显著.
The 7×××series aluminum alloy is mainly produced using semi-continuous water-cooled casting with this method,the solidification speed of the alloy is fast,leading to different degrees of dendrite segregation and non-equilibrium eutectic structure in the ingot.This also results in non-uniformity of composition and structure.Further,it adversely affects the subsequent cutting process and comprehensive performance of the alloy.Therefore,ingot homogenization becomes an indispensable and very critical process for the elimination of segregation.There is much research on Al-Zn-Mg-Cu alloys at home and abroad at the present.This research mainly concentrates on alloys such as 7075,7050,7150 and 7055.The content of the main alloying elements of these alloys is mostly around10%.However,at present,there is not much research on alloy materials with a strength and main alloying element content exceeding12.5%.The main alloy element content of 7136 aluminum alloy is about 13.5%.In 7136 aluminum alloy,the main alloy element content is high and the cast microstructure characteristics and homogenization treatment conditions are very different from other 7×××series aluminum alloys.In this paper,semi-continuous casting 7136 aluminum alloy was taken as the research object,based on the ascast microstructure analysis,using two-stage homogenization.The results show that,compared with the other 7×××series aluminum alloys,the cast microstructure of 7136 aluminum alloy has no obvious lamellar Al(Al)+T eutectic phase characteristics,and no S phase exists.The dispersed phase in the matrix is a micron-sized round or rod-shaped MgZn2 phase.The Mg and Zn were precipitated as MgZn2 phase in the Al matrix as the liquid alloy solidified.In order to balance the partition coefficients of the Mg and Zn,the two metals converted from the liquid to the solid state,which explained why the Zn and Mg crystal contents were high.After a single stage of homogenization at 462℃,24 h,the residual phase was substantially eliminated.As the homogenization
作者
李佳乐
周成
黄旭东
张志豪
吕丹
LI Jia-le;ZHOU Chen;HUANG Xu-dong;ZHANG Zhi-hao;LüDan(School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China;Institute for Advanced Materials and Technology,University of Science and Technology Beijing,Beijing 100083,China;Northeast Light Alloy Co.LTD,Harbin 150060,China)
出处
《工程科学学报》
EI
CSCD
北大核心
2019年第7期914-921,共8页
Chinese Journal of Engineering
基金
国家重点研发计划资助项目(2016YFB0300900)
NSFC-辽宁联合基金资助项目(U1708251)
东北轻合金有限责任公司铝镁合金材料院士工作站资助项目
关键词
7136超高强铝合金
半连续铸造
MgZn2相
铸态组织
均匀化热处理
7136 ultra-high strength aluminum alloy
semicontinuous casting
MgZn2 phase
cast microstructure
homogeneous heat treatment
