摘要
A new complex, [Ni（H2O）6][Mo2O2S2（edta）]·2H2O （1, edta = ethylenediamine- tetraacetate）, which was partially-sulfided, was synthesized and characterized by single-crystal X-ray diffraction. Compound 1 belongs to the monoclinic system, C2/c space group with a = 7.1844（2）, b = 12.5626（4）, c = 27,0201（8） A, β= 93,066（3）°, V = 2435.21（14） A3, C10H28S2Mo2N2NiO18, Mr= 779.02, Dc= 2.1247 g/cm3, A,（MoKa） = 2.035 mml, F（000） = 1550, Z = 4, the final R = 0.0366 and wR = 0.0656 for 5359 observed reflections （I 〉 2σ（I））. There are one isolated [Ni（H2O）6]^2＋ cation and one [Mo2O2S2（edta）]^2- anion in its asymmetric unit, and they are connected through multiple hydrogen bonds to generate a 3D network. In addition, the thermal behavior of compound 1 and the hydrodesulfurization activity of the catalyst derived from compound 1 were studied.
A new complex, [Ni（H2O）6][Mo2O2S2（edta）]·2H2O （1, edta = ethylenediamine- tetraacetate）, which was partially-sulfided, was synthesized and characterized by single-crystal X-ray diffraction. Compound 1 belongs to the monoclinic system, C2/c space group with a = 7.1844（2）, b = 12.5626（4）, c = 27,0201（8） A, β= 93,066（3）°, V = 2435.21（14） A3, C10H28S2Mo2N2NiO18, Mr= 779.02, Dc= 2.1247 g/cm3, A,（MoKa） = 2.035 mml, F（000） = 1550, Z = 4, the final R = 0.0366 and wR = 0.0656 for 5359 observed reflections （I 〉 2σ（I））. There are one isolated [Ni（H2O）6]^2＋ cation and one [Mo2O2S2（edta）]^2- anion in its asymmetric unit, and they are connected through multiple hydrogen bonds to generate a 3D network. In addition, the thermal behavior of compound 1 and the hydrodesulfurization activity of the catalyst derived from compound 1 were studied.
基金
Supported by the National Natural Science Foundation of China(No.21206197)
Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province(BS2013CL021)
Undergraduate Innovative Training Program of Shengli College of China University of Petroleum(20141001)
