摘要
聚离子液体(Poly(ionic liquid)s)是指由离子液体单体聚合生成的,在重复单元上具有阴、阳离子基团的一类离子聚合物。功能化聚离子液体是由功能化离子液体发展而来,兼具离子液体和高分子聚合物的性质。该类研究着眼于结构可控性质,设计合成具有特殊性能的、稳定的、功能化材料。近年来已经在高分子化学、电化学、材料科学及能源科学等领域得到初步应用。本论文综述聚离子液体在固态电解质和聚电解质膜、智能响应性功能材料,以及聚离子液体基碳材料、聚离子液体/碳纳米杂化材料、催化等相关领域的研究与应用。
Poly（ionic liquid）s （or polymerized ionic liquids, PILs） are defined by the polyelectrolytes generated from ionic liquid monomers, with cations and anions in the repeating units. PlLs combines the advantages of both ionic liquids and polymers. Researches work on designing and synthesizing the new and stable materials with specific functions based on the designability of PlLs molecules. The functional PIL materials have been preliminarily applied in the fields of polymer chemistry, electrochemistry, energy and material science recently. This review introduces and discusses the new applications of poly（ionic liquid）s, including solid-state electrolyte, polyelectrolyte membrane, smart responsive materials, PILs/carbon hybrid materials, carbonaceous material derived from poly（ionic liquid）s and catalysis.
出处
《高分子通报》
CAS
CSCD
北大核心
2015年第10期94-104,共11页
Polymer Bulletin
基金
国家杰出青年基金(No.21425417)
国家自然科学基金(No.21274101)资助
关键词
聚离子液体
准固态电解质
改性
碳材料
智能响应
Poly（ionic liquid） s
Solid-state electrolytes
Modification
Carbon materials
Smart responsive
