期刊文献+

pH振荡研究型化学实验 被引量:1

A Research-Oriented Chemical Experiment on p H Oscillation
下载PDF
导出
摘要 Br O-3-SO2-3-Fe(CN)4-6(BSF)是典型的p H振荡反应。该振荡具有振幅大,振幅和周期易于调节,且可偶合p H敏感性材料实现p H刺激下的其他振荡行为转换的特点。与传统物理化学实验中的B-Z振荡相比,该振荡具有更强的拓展性,适合作为综合型或研究型实验,对于培养学生创新能力与综合科研能力具有积极意义。 BrO-3-SO2-3-Fe( CN)4-6( BSF) is a typical p H oscillating system with the large amplitude. The amplitude and period of this oscillation are adjustable. And this oscillation can be combined with p H sensitive materials in order to carry out to facilitate the transformation of other oscillation behaviors with the p H stimulation. Compare with the traditional B-Z oscillation in physical chemistry experiment,this p H oscillation based experiment can be expanded for comprehensive or research-oriented experiment,which is helpful for the comprehensive ability and the innovation ability training.
出处 《大学化学》 CAS 2015年第5期45-51,共7页 University Chemistry
基金 陕西省自然科学基础研究计划资助项目(No.2013JQ2021)
关键词 pH振荡 溴酸盐-亚硫酸盐-亚铁氰化物(BSF)体系 振荡行为 活化能 pH oscillation Bromate-sulfite-ferrocyanide(BSF) system Oscillating behavior Activation energy
  • 相关文献

参考文献18

  • 1张媛媛..pH振荡和pH-Ca2+复合振荡反应研究[D].首都师范大学,2009:
  • 2复旦大学.物理化学实验.第3版.北京:高等教育出版社,2006. 被引量:1
  • 3董小梅,刘剑波,徐功骅.B—Z振荡反应[J].大学化学,1996,11(2):35-37. 被引量:2
  • 4Luo Y,Epstein I K. J Am Chem Soc,1991,113(5) :1518. 被引量:1
  • 5Poras E, Horvath V,Kurin-CsOrgei K,ei al. J Am Chem Soc,2011,133( 18) :7174. 被引量:1
  • 6Kurin-CsOrgei K,Epstein I R,Orbdn M. Nature,2005,433(1) : 139. 被引量:1
  • 7Liedl T,Simmel F C. Nano Lettt2005 ,5( 10) :1894. 被引量:1
  • 8Nabika H,Oikawa T,Iwasaki Kfet al. J Phys Chem C,2012,116( 10) :6153. 被引量:1
  • 9Buyukcakir 0,Yasar F T,Bozdemir 0 A,et al. Org ,2013 ,15 (5 ) :1012. 被引量:1
  • 10Tian E,Ma Y,Cui h,et al. Macromol Rapid Commun,2009,30(20) :1719. 被引量:1

二级参考文献19

  • 1POROS E, HORVJ:TH V, KURIN-CSORGEI K, et al. Generation of pH-oscillations in closed chemical systems: method and applications [ J ]. J Am Chem Soc, 2011, 133(18) : 7174-7179. 被引量:1
  • 2ORB:N M, EPSTEIN I R. A new halogen-free chemi-ca] oscillator: the reaction between sulfide ion and hy- drogen peroxide in a CSTR [ J]. J Am Chem Soc, 1985, 107(8) : 2302-2305. 被引量:1
  • 3SATO N, HASEGAWA H H, KIMURA R, et al. A- nalysis of the bromate-sulfite-ferrocyanide pH oscilla- tor using the particle filter: toward the automated modeling of complex chemical systems [ J ]. J Phys Chem A, 2010, 114(37) : 10090-10096. 被引量:1
  • 4TIAN E, MA Y, CUI L, et al. Color-oscillating pho- tonic crystal hydrogel [ J ]. Macromol Rapid Com- mun, 2009, 30(20): 1719-1724. 被引量:1
  • 5KURIN-CSORGEI K, EPSTEIN I R, ORB:N M. Sys- tematic design of chemical oscillators using complex- ation and precipitation equilibria [J]. Nature, 2005, 433 ( 1 ) : 139-142. 被引量:1
  • 6JI L, WANG H Y, HOU X T. Complexation amplified pH oscillation in metal involved systems [ J ]. J Phys Chem A, 2012, 116(28) : 7462-466. 被引量:1
  • 7TAYLOR A F, KOVACS K, SCOTI" S K. Nonlinear pH responsive chemomechanical devices [ J ]. Poly- mer Preprints, 2008, 49 ( 1 ), 804. 被引量:1
  • 8LIEDL T, SIMMEL F C. Switching the conformation of a DNA molecule with a chemical oscillator [ J]. Nano Lett, 2005, 5(10): 1894-1898. 被引量:1
  • 9NABIKA H, OIKAWA T, IWASAKI K, et al. Dy- namics of gold nanoparticle assembly and disassembly induced by pH oscillations [ J ]. J Phys Chem C, 2012, 116(10): 6153-6158. 被引量:1
  • 10NAKAGAWA H, HARA Y, MAEDA S, et al. A pen- dulum-like motion of nanofiber gel actuator synchro- nized with external periodic pH oscillation [ J ]. Poly- mers, 2011, 3(1): 405-412. 被引量:1

共引文献4

同被引文献1

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部