摘要
The Fe3＋/Fe2＋ redox electrolyte for use in polyaniline/tin oxide （PANI/SnO2）supercapacitors was reported. The influences of redox electrolyte based on different Fe3＋/Fe2＋ ion pair concentrations in 1 mol/LH2SO4 solution on the pseudocapacitive behaviors of PANI/SnO2 supercapacitor were investigated. The electrochemical properties of the supercapacitor were studied by cyclic voltammetry （CV）, galvanostatic charge discharge （GCD）, and electrochemical impedance spectroscopy （EIS） techniques. It is found that the performance of the supercapacitor is the best when the Fe3＋/Fe2＋ concentrationis 0.4 mol/L and its initial specific capacitance is 1172 F/g at an applied current density of 1 A/g. The long-term cycling experiment shows good stability with the retention of initial capacitance values of 88% after 2000 galvanostatic cycles. The experimental results testify that using Fe3＋/Fe2＋ redox electrolyte has a good prospect for improving the performances of energy-storage devices.
报道Fe3+/Fe2+氧化还原电解液在聚苯胺/SnO2超级电容器中的应用,研究不同浓度的Fe3+/Fe2+离子对与1 mol/L H2SO4溶液组成的氧化还原电解液在超级电容器中的赝电容行为。用循环伏安法、恒电流充放电法和交流阻抗法对超级电容器的电化学性能进行研究。当Fe3+/Fe2+浓度为0.4 mol/L时,超级电容器的性能最好,其在1A/g电流密度下的比容量达到1172 F/g。将聚苯胺/SnO2超级电容器进行长期的循环实验,经过充放电循环2000次后,其起始容量保持率达到88%。实验结果表明,使用Fe3+/Fe2+氧化还原电解液来提高能量储存装置的性能具有很好的前景。
基金
Project(51172190)supported by the National Natural Science Foundation of Nation
Project(07JJ6015)supported by the Natural Science Foundation of Hunan Province,China
