摘要
The vanadium titano-magnetite （VTM） iron ore fines of 110--150/xm in diameter were reduced in a trans- parent quartz fluidized bed by 70 %CO-30 % H2 （volume fraction） mixtures. MgO powders served as coating agent to solve sticking problem. Two coating methods were introduced in this experiment： high temperature injection method and briquetting→oxidizing roast→crushing method. According to the experimental results, the minimum effective coating amount of MgO was 0. 1 mass%. The metallization ratio （MR） of the product rose from around 58% to above 90% with the above treatments. To investigate the sticking mechanism of fine ore, the morphology evolution was in- vestigated. Instead of iron whiskers, an interlaced fibrous porous surface formed. The ulvospinel （2FeO ： TiO2 ） in VTM is more difficult to be reduced than FeO according to thermodynamic calculation. XRD results showed that MgO diffused into Fe203 lattice before forming pleonaste （MgO · Fe2O3 ） during oxidizing roast at 1273 K. The melting point of the pleonaste is 1986 K and that made contribution to prevent the sticking problem.
The vanadium titano-magnetite （VTM） iron ore fines of 110--150/xm in diameter were reduced in a trans- parent quartz fluidized bed by 70 %CO-30 % H2 （volume fraction） mixtures. MgO powders served as coating agent to solve sticking problem. Two coating methods were introduced in this experiment： high temperature injection method and briquetting→oxidizing roast→crushing method. According to the experimental results, the minimum effective coating amount of MgO was 0. 1 mass%. The metallization ratio （MR） of the product rose from around 58% to above 90% with the above treatments. To investigate the sticking mechanism of fine ore, the morphology evolution was in- vestigated. Instead of iron whiskers, an interlaced fibrous porous surface formed. The ulvospinel （2FeO ： TiO2 ） in VTM is more difficult to be reduced than FeO according to thermodynamic calculation. XRD results showed that MgO diffused into Fe203 lattice before forming pleonaste （MgO · Fe2O3 ） during oxidizing roast at 1273 K. The melting point of the pleonaste is 1986 K and that made contribution to prevent the sticking problem.
基金
Sponsored by National Natural Science Foundation of China(51234001)
National Basic Research Program of China(2012CB720401)
