摘要
详细介绍了一类KF促进的酚与三氟甲基三甲基硅烷的三甲基硅基化反应.反应具有良好的官能团适用范围,如带有甲基、甲氧基、碘、溴、氯、氟及三氟甲基等官能团的酚都能够顺利发生该转化.该方法给出了一类实用性强的三甲基硅基芳醚的合成途径.
This paper introduces in detail the reaction with KF-accelerant trimethylsilylation of phenols with trifluormethyltrimethylsilane. The procedure tolerates a series of functional groups, such as methyl, methoxy, iodo, bromo, chloro, fluoro and trifluoromethyl groups. Thus, the approach represents a practical synthetic route to access trimethylsilyl ethers.
出处
《温州大学学报（自然科学版）》
2015年第2期51-57,共7页
Journal of Wenzhou University(Natural Science Edition)
