摘要
Mesoporous N-doped carbon supported palladium catalyst Pd@CN0.132 was able to efficiently catalyze unprotected indole to indoline under mild conditions.In the aqueous system,a selectivity of 100% and conversion of 96% was achieved under 313 K and atmospheric hydrogen gas.
Mesoporous N-doped carbon supported palladium catalyst Pd@CN0.132 was able to efficiently catalyze unprotected indole to indoline under mild conditions.In the aqueous system,a selectivity of 100% and conversion of 96% was achieved under 313 K and atmospheric hydrogen gas.
基金
support from the Joint Petroleum and Petrochemical Funds of the National Natural Science Foundation of China
China National Petroleum Corporation (No.U1162124)
the Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China (No.LR13B030001)
the Specialized Research Fund for the Doctoral Program of Higher Education (No.J20130060)
the National Natural Science Foundation of China (No.21206085)
Excellent Middle-aged and Young Scientists Research Award Foundation of Shandong Province (No.BS2011CL023)
the Fundamental Research Funds for the Central Universities,the Program for Zhejiang Leading Team of S&T Innovation,and the Partner Group Program of Zhejiang University and the Max-Planck Society are greatly appreciated