摘要
Two-dimensional FT-IR correlation spectroscopy was used to reveal the structural changes of isotactic polypropylene(iPP) mesophase during the heating process.The co-relationship among the regular helical bands of iPP was discussed according to synchronous spectrum.The results show that the segments with different length-helixes were found to undergo a disordered process in the temperature range of 25-60 ℃.
Two-dimensional FT-IR correlation spectroscopy was used to reveal the structural changes of isotactic polypropylene(iPP) mesophase during the heating process.The co-relationship among the regular helical bands of iPP was discussed according to synchronous spectrum.The results show that the segments with different length-helixes were found to undergo a disordered process in the temperature range of 25-60 ℃.
基金
financially supported by the National Natural Science Foundation of China(No.51373003)