期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Hydrothermal Synthesis of MoO_2 and Supported MoO_2 Catalysts for Oxidative Desulfurization of Dibenzothiophene 被引量：7

Hydrothermal Synthesis of MoO_2 and Supported MoO_2 Catalysts for Oxidative Desulfurization of Dibenzothiophene
下载PDF
导出
摘要 A novel method for obtaining spherical MoO2 nanoparticles and SiO2-Al2O3 supported MoO2 by hydrothermal reduction of Mo(VI) species was studied. The obtained MoO2 catalysts show very high catalytic activity in the oxidative desulfurization(ODS) process. The effect of hydrothermal temperature and crystallization temperature on ODS activity was investigated. The ODS activity of supported MoO2 catalysts with various MoO2 contents were also investigated. The mechanism for formation of MoO2 involving oxalic acid was proposed. A novel method for obtaining spherical MoO2 nanoparticles and SiO2-Al2O3 supported MoO2 by hydrothermal reduction of Mo (VI) species was studied. The obtained MoO2 catalysts show very high catalytic activity in the oxidative desulfurization (ODS) process. The effect of hydrothermal temperature and crystallization temperature on ODS activity was investigated. The ODS activity of supported MoO2 catalysts with various MoO2 contents were also investigated. The mecha-nism for formation of MoO2 involving oxalic acid was proposed.
作者 Wang Danhong Zhang Jianyong Liu Ni Zhao Xin Zhang Minghui
机构地区 Key Laboratory of Advanced Energy Materials Chemistry (MOE)
出处 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第4期19-23,共5页 中国炼油与石油化工（英文版）
基金 supported by the National Nature Science Foundation of China(NSFC grant No.21303088) the Natural Science Foundation of Tianjin(14JCYBJC20000) the MOE Innovation Team(IRT13022 and IRT13R30)of China
关键词 MoO2 HYDROTHERMAL reduction OXIDATIVE DESULFURIZATION NANOPARTICLE MoO2 hydrothermal reduction oxidative desulfurization nanoparticle
分类号 TE624.9 [石油与天然气工程—油气加工工程]
  • 相关文献

参考文献19

  • 1王广建,刘英环,曾娜,刘辉.Ti-HMS分子筛的制备与催化氧化脱硫性能研究[J].石油炼制与化工,2013,44(2):18-21. 被引量：4
  • 2Zhang J, Wang A, Li X, et al. Oxidative desulfurization ofdibenzothiophene and diesel over[Bmim]3PMo12O40[J]. JCatal, 2011, 279(2): 269-275. 被引量：1
  • 3Ishihara A, Wang D H, Dumeignil F, et al. Oxidative desulfurizationand denitrogenation of a light gas oil using anoxidation/adsorption continuous flow process[J]. Appl CatalA, 2005, 279(1/2): 279-287. 被引量：1
  • 4Chica A, Corma A, Domine M E. Catalytic oxidative desulfurization(ODS) of diesel fuel on a continuous fixed-bedreactor[J]. J Catal, 2006, 224(2): 299-308. 被引量：1
  • 5Prassad V V D N, Jeong K, Chae H, et al. Oxidative desulfurizationof 4,6-dimethyl dibenzothiophene and light cycleoil over supported molybdenum oxide catalysts[J]. CatalCommun, 2008, 9(10): 1966-1969. 被引量：1
  • 6赵荣祥,李秀萍.水热法制备WO_3微米棒及其催化脱除二苯并噻吩研究[J].石油炼制与化工,2012,43(11):47-50. 被引量：1
  • 7Rothlisberger A, Prins R. Intermediates in the hydrodesulfurizationof 4,6-dimethyl-dibenzothiophene over Pd/gamma-Al2O3[J]. J Catal, 2005, 235(1): 229-240. 被引量：1
  • 8Oyama S T, Zhao H, Freund H J, et al. Unprecedented selectivityto the direct desulfurization (DDS) pathway in ahighly active FeNi bimetallic phosphide catalyst[J]. J Catal,2012, 285(1): 1-5. 被引量：1
  • 9Wang D H, Qian E W H, Amano H, et al. Oxidative desulfurizationof fuel oil - Part I. Oxidation of dibenzothiophenesusing tert-butyl hydroperoxide[J]. Appl Catal A,2003, 253(1): 91-99. 被引量：1
  • 10Katrib A, Leflaive P, Hilarie L. Molybdenum based catalysts:I. MoO2 as the active species in the reforming ofhydrocarbons[J]. Catal Lett, 1996, 38 (1/2): 95-99. 被引量：1

二级参考文献27

共引文献4

同被引文献80

引证文献7

二级引证文献28

China Petroleum Processing & Petrochemical Technology
2014年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部