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硅钨酸盐/聚苯胺材料光催化降解龙胆紫 被引量:2

Photocatalytic Degradation of Gentian violet by Materials Silitungstate / PANI
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摘要 用自制的Si W11Cr/PANI为光催化剂,以龙胆紫溶液模拟工业染料废水,研究了Si W11Cr/PANI的光催化降解性能,实验主要考察了催化剂的用量、染料溶液的初始浓度、染料溶液的p H等对龙胆紫溶液脱色率的影响。实验表明,光催化降龙胆紫的最佳条件是:催化剂用量3 mg,p H值为3,染料溶液初始浓度为15 mg/L,紫外灯光照170 min,脱色率为97.97%。 The gentian violet solution was used as simusated dye wastewater and the photocatalytic activity of materials Si W11 Cr / PANI were studied. The effects of the initial concentration of the gentian violet in the catalyst quantity and the solution p H on decolorizing efficiency of the solution were discussed in detail. The degradation rate of gentian violet in with Si W11 Cr / PANI was 97. 97% after being treated for 170 min under the UV light irradiation at p H 3,using 15 mg / L.
出处 《广州化工》 CAS 2015年第1期62-64,共3页 GuangZhou Chemical Industry
基金 黑龙江省教育厅基金资助(No:12531760)
关键词 钨硅酸盐 光催化剂 龙胆紫 降解 silicotungstate photocatalytic gentian violet degradation
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参考文献8

  • 1华英杰,王崇太,孙振范,刘艳玲,周昌盛.新颖的PW_(11)O_(39)Fe(Ⅲ)(H_2O)^(4-)/H_2O_2类光-芬顿体系光催化降解苯胺[J].应用化学,2012,29(1):63-68. 被引量:8
  • 2陈发旺,胡长文.多金属氧簇催化研究进展[J].化学进展,2011,23(1):19-41. 被引量:20
  • 3Qua X S, Guo Y H, Hu C W, et al. Preparation and heterogeneous photocatalytic activity of mesoporous HaPW12 040/ZrO2composites [ J ]. Journal of Molecular Catalysis A: Chemical, 2011,262(1-2) : 128-135. 被引量:1
  • 4Li G X, Ding Y, Wang J M, et al. New Progress of Keggin and Wells- Dawson type Polyoxometalates catalyze acid and oxidative reactions[J]. Journal of Molecular Catalysis A,2007,262 ( 2 ) :67-76. 被引量:1
  • 5Jiang S J, Guo Y H, Wang C H, et al. One-step sol-ge! preparation and enhanced photocatalytic activity of porous polyoxometalate-tantalum pentoxide nanocomposites [ J ]. Journal of Colloid and Interface Science, 2012, 308( 1 ) : 208-215. 被引量:1
  • 6Tai H L, Jiang Y D, Xie G Z, et al. Preparation, characterization and comparative sensing characteristic studies of PANI/inorganie oxides [J]. Mater. Sci. Teehnol. , 2011 , 26(7) : 605-613. 被引量:1
  • 7Ma R H. Synthesis and properties of polyaniline doped with iron- substituted silicotungstate isomers with Keggin structure [ J ]. J Coord Chem,2008,61 (7) : 1056-1065. 被引量:1
  • 8王恩波等著..多酸化学导论[M].北京:化学工业出版社,1998:285.

二级参考文献23

  • 1王春刚,姜春杰,胡长文.Dawson结构杂多酸盐催化合成碳酸丙烯酯[J].高等学校化学学报,2004,25(7):1325-1327. 被引量:15
  • 2周广栋,甄开吉,王海水,程铁欣.杂多化合物及其负载型催化剂的研究进展[J].化学进展,2006,18(4):382-388. 被引量:12
  • 3Zhao X K, Yang G P, Wang Y J, et al. Photochemical Degradation of Dimethyl Phthalate by Fenton Reagent [ J ]. Photochem Photobiol, A Chem, 2004,161 ( 3 ) : 215-220. 被引量:1
  • 4Fukushima M, Tatsumi K, Morimoto K. The Fate of Aniline after a Photo-Fenton Reaction in an Aqueous System Containing Iron ( III ), Humic Acid, and Hydrogen Peroxide [ J ]. Environ Sci Technol,2000,34 (10) :2006-2013. 被引量:1
  • 5Toth J E, Anson F C. Electrochemical Properties of Iron ( III ) -substituted Heteropolytungstate Anions [ J ]. J Electroanal Chem, 1988,256 ( 2 ) : 361-370. 被引量:1
  • 6Toth J E, Anson F C. Electrocatalytic Reduction of Nitrite and Nitric Oxide to Ammonia with Iron-Substituted Polyoxotungstates [ J ]. J Am Chem Soc , 1989,111 (7) :2444-2451. 被引量:1
  • 7Zonnevijlle F, Tourne C M, Tourne G F. Preparation and Characterization of Iron ( Ⅲ )- and Rhodium ( Ⅲ ) -Containing Heteropolytungstates Identification of Novel Oxo-Bridged Iron (Ⅲ) Dimers[ J ]. Inorg Chem, 1982,21 (7):2751-2757. 被引量:1
  • 8Brevard C, Schimpf R, Tourne G, et al. Tungsten-183 NMR:A Complete and Unequivocal Assignment of the Tungsten- tungsten Connectivities in Heteropolytungstates via Two-dimensional ^183W NMR Techniques[ J]. J Am Chem Soc, 1983,105 ( 24 ) :7059-7063. 被引量:1
  • 9Oturan M A,Pinson J. Hydroxylation by Electrochemically Generated OH Radicals. Mono- and Polyhydroxylation of Benzoic Acid: Products and Isomers' Distribution [ J ]. J Phys Chem B, 1995,99 ( 38 ) : 13948-13954. 被引量:1
  • 10Wang Chongtai, Hua Yingjie, Tong Yexiang. A Novel Electro-Fenton-Like System Using PWI1039 Fe ( Ⅲ ) ( H2 O) ^4 - as an Eleetrocatalyst for Wastewater Treatment [ J ]. Electrochim Acta, 2010, 55 ( 22 ) : 6755-6760. 被引量:1

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