摘要
将磷钼杂多酸聚吡咯(PMo12-PPY)用电聚合法沉积在载有多孔阳极氧化铝(AAO)的玻碳电极表面(AGCE),制备了PMo12-PPY/AGCE纳米复合材料修饰电极,并通过循环伏安(CVs)、电化学阻抗谱(EIS)方法表征了PMo-PPY/AGCE和PMo-PPY/GCE的电化学性质及电极界面反应特征.结果表明,AAO膜使电极表面粗糙度降低,电子传输的能力增强,并使氧化还原反应速度加快.
The PMO12-PPY/AGCE nanocomposite modified electrode prepared by electrodeposition of Polyoxometalates - polypyrrole（PMo12-PPY）on the glass carbon electrode covered with a macroporous alumina membrane（AAO）. Electrochemical property and electrode interface reaction characteristics of PMo-PPY/AGCE and PMo-PPY/GCE were analysed with the cyclic voltammograms（CVs） and elec- trochemical impedance （EIS）. The results indicated that macroporous AAO membrane can reduce roughness of modified electrode surface, enhance the ability of electronic transmission and accelerate the speed of redox reaction.
出处
《分子科学学报》
CAS
CSCD
北大核心
2014年第5期416-420,共5页
Journal of Molecular Science
基金
吉林省科技厅资助项目(20140204085GX)
关键词
阳极氧化铝
纳米复合材料
修饰电极
电化学交流阻抗
anodic aluminum oxide
nanocomposite
modified electrode
electrochemical impedance
