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石墨的形貌及粒径对锂离子电池性能的影响 被引量:9

Effects of shape and particle size of graphite on the performance of Li-ion battery
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摘要 采用D50为10μm的中间相碳微球(MCMB)、D50为10μm的层状石墨和D50为15μm的层状石墨制备实验电池,并研究了电池的性能。在2.5—3.7V循环,MCMB、D50为10μm的层状石墨和D50为15μm的层状石墨制备的电池的5.0C放电容量保持率分别为95.6%、94.2%和91.3%;1.0C充电、3.0C放电、100%放电深度(DOD)循环1600次的容量保持率分别为85.6%、84.4%和80.4%。同等粒径下,球形的MCMB相对于层状石墨有较好的倍率及循环性能;相同形貌下,粒径较小的石墨具有较好的倍率及循环性能。 Experimental battery was prepared by using mesocarbon microbeads (MCMB ,D50 = 10 μm),layered graphite (D50 = 10 μm) and layered graphite (D50 = 15 μm) ,the performance of the battery was studied. When cycled in 2. 5 -3.7 V,the 5.0 C discharge capacity retention of battery prepared with MCMB,layered graphite of Ds0 = 10 μm and layered graphite of D50 = 15 μm were 95.6% ,94. 2% and 91.3%, respectively, capacity retention was 85.6%, 84. 4% and 80. 4% when cycled 1 600 times with 1.0 C charge ,3.0 C discharge, 100% depth of discharge(DOD). In the same particle size, MCMB had better rate and cycle performance compared with layered graphite;in the same shape, graphite with small particle size had better rate and cycle performance.
出处 《电池》 CAS CSCD 北大核心 2014年第3期171-173,共3页 Battery Bimonthly
关键词 锂离子动力电池 倍率 形貌 粒径 power Li-ion battery rate performance shape particle size
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