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PmClAn基膜修饰电极的电化学及催化性质研究 被引量:3

Studies on Electrochemical and Catalytic Properties of Poly-m-chloraniline Modified Electrode
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摘要 The electrochemical and catalytic properties of PmClAn modified electrode were studied by cyclic voltammetry. The results showed that PmClAn had an excellent electroactivity and proton doping increased the electroactivity. The Pt particles electrodeposited on PmClAn trend towards preferred orientation, and Pt(200) was the preferred face. It was also found that platinized PmClAn promotes isopropanol oxidation, the polymer is not only as a dispersion media of Pt particles forming a "microheterogeneous catalysis system", but also has effect on electronic properties of Pt. The electrochemical and catalytic properties of PmClAn modified electrode were studied by cyclic voltammetry. The results showed that PmClAn had an excellent electroactivity and proton doping increased the electroactivity. The Pt particles electrodeposited on PmClAn trend towards preferred orientation, and Pt(200) was the preferred face. It was also found that platinized PmClAn promotes isopropanol oxidation, the polymer is not only as a dispersion media of Pt particles forming a 'microheterogeneous catalysis system', but also has effect on electronic properties of Pt.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第6期1174-1176,共3页 Chemical Journal of Chinese Universities
基金 国家教育部博士点专项科研基金项目 (批准号 :19990 3 840 4) 中 -法先进研究计划 (PRA-2 0 0 1)资助
关键词 膜修饰电极 电化学 催化性质 聚间氯苯胺 金属化聚合物 异丙醇 电催化氧化 化学包修电极 Poly m chloroaniline Metallized polymer Isopropanol oxidation Chemically modified electrodes
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