摘要
以纯化硅藻土和热活化高岭土为硅铝原料,在水热条件下一步合成纯相ZSM-5分子筛。考察分子筛合成参数对产物的影响,得到合成ZSM-5分子筛的适宜条件:硅藻土与高岭土质量比32∶1,晶化温度170℃,晶化时间48 h,合成体系pH=13. 0。采用XRD、SEM及N2吸附-脱附等对样品进行表征。结果表明,最适宜条件下合成的ZSM-5分子筛晶型完整,具有与工业ZSM-5分子筛相似的六棱柱形貌以及相近的总比表面积和总孔容。
Pure ZSM-5 zeolites were synthesized by conventional hydrothermal method using purified diatomite and heat-activated kaolin as silicon-aluminum raw materials. The effects of synthesis conditions of ZSM-5 zeolites were examined. The optimum conditions were as follows: the mass ratio of diatomite to kaolin was 32∶ 1,the crystallization temperature was 170 ℃,the crystallization time was 48 h,and the pH was 13. 0. The obtained materials were characterized by XRD,SEM and N2adsorption-desorption. The results indicated that the high purity ZSM-5 zeolites synthesized under the optimum conditions have the same regular hexagonal prism morphology as commercial ZSM-5 zeolites. The as-synthesized products with high degree of crystallinity also had large total specific surface area and pore volume.
作者
徐经纬
苏熹
周相娜
刘元良
王有和
Xu Jingwei;Su Xi;Zhou Xiangna;Liu Yuanliang;Wang Youhe(State Key Laboratory for Heavy Oil Processing,China University of Petroleum,Qingdao 266580,Shandong,China;College of Science in China University of Petroleum (Huadong),Qingdao 266580,Shandong,China)
出处
《工业催化》
CAS
2018年第11期88-92,共5页
Industrial Catalysis
基金
山东省自然科学基金(ZR2016BM28)
