摘要
研究了相转移催化剂 (Bu4 NHSO4 )作用下苄基醚用双媒质 Cr( ) / Ag( )体系选择性间接电氧化 .苄基醚氧化裂解生成脂肪醇和苯甲醛 .0 .0 1mol/ L Ag( )能够使 Cr( )氧化电流效率高 .双媒质体系可以循环使用 .
The selective indirect electrical oxidation of benzyl ethers was studied with the double mediators under phase transfer catalysis (tetrabutyl ammonium hydrogen sulphate). Benzyl ethers were oxidized and cloven to prepare aliphatic alcohol and benzaldehyde. About 0 01 mol/L Ag(Ⅰ) was needed to obtain better current efficiency. The double mediators may be recycled.
出处
《兰州大学学报（自然科学版）》
CAS
CSCD
北大核心
2001年第4期60-63,共4页
Journal of Lanzhou University(Natural Sciences)
基金
国家自然科学基金 (6 98710 13)资助项目
