摘要
运用原子簇化合物键价计算公式 ,对过渡金属卤素和氧簇合物成键情况进行了分析 .这类簇合物既可以形成 M M多重键 ,又具有空轨道 ,可增加σ配体 。
The formation situation of the bond for transition metallic halide and carboxylate Cluster compounds is analysed with the bond vanlence formula for atomic cluster compounds.This cate gory cluster compounds not only formed M-M multiple bonds,but also had empty orbits.The σ ligends can be addeing.The total of VBMO and the number of metal bonding MO is linear.
出处
《河北师范大学学报（自然科学版）》
CAS
2001年第4期493-495,共3页
Journal of Hebei Normal University：Natural Science
