摘要
应用交流伏安法和线性电位扫描法研究了Pb ,Pb 1.0at%La和Pb 1.0at%Sm电极在硫酸溶液中以 0 .9V(vs .Hg/Hg2 SO4 )生长的阳极Pb(Ⅱ )膜增长率和膜的阻抗实部变化 ,并采用循环伏安法研究了它们在 0 .6～ 1.6V(vs.Hg/Hg2 SO4 )间的循环伏安特性 ,结果表明 :在铅中添加Sm有利于抑制铅的阳极腐蚀和降低阳极Pb(Ⅱ )膜的阻抗 ,La亦可降低阳极Pb(Ⅱ )膜的阻抗 。
AC voltammetry,linear sweep voltammetry,and cyclic voltammetry were applied to study the anodic corrosion of Pb,Pb 1.0at%La and Pb 1.0at%Sm electrodes in 4.5 mol·dm -3 H 2SO 4 solution (25 ℃).The experiment results show that samarium can inhibit the anodic corrosion of lead and decrease the impedance of anodic Pb(Ⅱ) film. Lanthanum can also decrease the impedance of the anodic Pb(Ⅱ)film, but the effect is smaller.
出处
《电化学》
CAS
CSCD
2001年第4期439-444,共6页
Journal of Electrochemistry
基金
国家自然科学基金 (2 98730 13)资助项目
