摘要
从液体汽化机理出发，按照液体分子运动理论导出 和γｂ＝ ４．１８７×１０－３（１８．２Ｔｂ＋３．２Ｔｃ—７８０），进而应用有机分子的半金属结构理论的理论定则及分子物理学与光谱学的理论和实验成果，运用矩阵理论导出沸点下液体汽化热理论方程．经以 ３６种不同结构类型的极性与非极性的２２８种纯质实验值检验平均误差仅０．８％误差＜２％的占总数９５％以上，物理意义明确，有重要的理论价值和广泛的实用价值，显著优于文献中各式．
On the basis of the Clausius - Clapeyron equation and the kinetic theory of liquid we obtained γｂ＝ ４．１８７×１０－３（１８．２Ｔｂ＋３．２Ｔｃ—７８０） And according to the rules of semi - metal structural theoretic model of organic molecules and the theoretic and experimental results from molecular physics, spectroscopy and matrix method, a new theoretic equation (Eq.5) for calculating enthalpy of vaporization γb at normal boiling point is derived. Eq5 is simple and reliable for calculating γb． The values Ci and Ce, required in this equation can be found in Table 3. This equation can be applied both to nonpolar and polar liquids. The average error from experimental data is 0.8% based upon 228 compounds of 36 types of structures. It is far better than all other methods in literature. The physical essence of Eq.5 is clear and definite. This work is of important in the development of engineering thermodynamics and its practical application.
出处
《黑龙江大学自然科学学报》
CAS
2001年第3期71-76,共6页
Journal of Natural Science of Heilongjiang University
基金
国家自然科学基金委员会科学部主任基金资助(No.29746002)
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