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Ar·O准分子位能曲线计算及新的荧光辐射带

The Calculation of Potential Energy Curve and The New Emission Band of Ar·O Excimer Molecule
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摘要 1 引言 Xe·O准分子辐射谱的研究早从1941年开始。Powell在Xe-O<sub>2</sub>,K<sub>r</sub>-O<sub>2</sub>混合系统里发现了绿色荧光辐射带,这些辐射带都在558nm附近,也就是靠近O(<sup>1</sup>S<sub>0</sub>-<sup>1</sup>D<sub>2</sub>)和O(<sup>1</sup>S<sub>0</sub>-<sup>3</sup>P<sub>1</sub>)谱线。这表明这类准分子是一种弱的束缚态。对氧原子而言,O(<sup>1</sup>S<sub>0</sub> In this paper we calculated the potential energy curve, transition rate, molecularconstants for Ar.O excimer molecule using discharge to excite Ar--O_2 system. Thewave lengths of the peak are 5690A and 5696A. It is from the transition betweenAr. O(2~1Σ) and Ar. O(1~1Π). The transition rate of calculation is A_(ik)(2~1Σ--1~1Π) =0. 21×10~8/秒. The experemental values are in agreement with the results of thecalcu lations,It is useful for researching the New emission bands and may be a laserpotential energy system.
出处 《量子电子学》 CSCD 1991年第4期426-430,共5页
关键词 准分子 位能曲线 计算 荧光 辐射带 potential energy Ar·O eximer molecule new emission band
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