摘要
提出在0.12 mol/L HCl－0.004 g/L连苯三酚－0.000 02 g/L偏钒酸铵的混合底液中，用二次导数，阴极化扫描示波极谱法测定微量锗。Ep约－0.68 V。在0～1 μg/10 mL时Ip与浓度线性良好，检出下限可达4 ng/mL。本文采用在9.6 mol/L HCl中用苯萃取锗的方法分离获得满意结果。
This paper reports the determination of trace germanium by oscillopolarographic in the mixture solution of 0.12 mol·L－1 HCl－0.004 g·L－1 1,2,3－Benzontrail－0.00002 g·L－1 Ammonium metavanadate.The peak potential is about 0.68 v(vs·SLE).In the range of 0～1μg·(10ml)－1 for the concetration of germanium,Ip Linear is good,and the detecting lower limit attains 0.04 μg·(10ml)－1 the result of isolating germanium from 9.6 mol·L－1 HCl by extration is satisfaetory.
出处
《湖南有色金属》
CAS
2001年第2期45-47,共3页
Hunan Nonferrous Metals
