摘要
用牺牲金属阳极的电化学方法合成了三种新的一价银配合物 Ag (I) (dppe) (CH(CN) 2 ) ,Ag(I) (dppe) (CH3COCHCOOEt)及 Ag(I) (dppe) (CH3COCHCOCH3) ,对配合物进行了元素分析、红外光谱测试及表征 ,并研究了反应的机理。
The complexes of silver(I) with ethylenebis(diphenylphosphine) and acetylacetone, ethylacetoacetate, malononitrile were prepared by an electrochemical method in nonaqueous solutions. The products were characterized by elemental analysis, IR measurements as Ag(I)(dppe)(CH(CN) 2), Ag(I)(dppe) ( CH 3COCHCOOEt) and Ag(I) (dppe) (CH 3COCHCOCH 3) respectively. The electrochemical reactions were also studied.
出处
《淮海工学院学报（自然科学版）》
CAS
2001年第3期39-41,共3页
Journal of Huaihai Institute of Technology:Natural Sciences Edition
