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甘油的化学转化研究概况 被引量:2

Survey of the Chemical Transformation Progress of Glycerol
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摘要 随着全球生物柴油产量的迅速增加,如何利用生物柴油副产的大量甘油已成为一个重要的研究课题。生物源甘油是一个多功能的绿色"平台分子",通过对其还原、氧化、重整(分解)、脱水、醚化及与其它试剂的反应可生成许多以石化为原料的产品。本文概述了近年来由甘油转化为各种化工产品的研究进展。 With the rapid increase in biodiesel production, the utilization of a large surplus glycerol as a byproduct from biodiesel manufacture has become an important topic. Glycerol is a green muhifunctional "platform molecule " Products from the chemical transformation of glycerol through hydrogenolysis (reduction), oxidation, reforming(pyrolysis), dehydration, etherification and some compounds by reacting it with other reagents can replace those based on the petrochemical raw materials. The latest transformation progress of glycerol into other chemical products was reviewed in this article.
出处 《应用化学》 CAS CSCD 北大核心 2014年第4期367-376,共10页 Chinese Journal of Applied Chemistry
基金 江苏省自然科学基金项目(BK2011235) 江苏省教育厅指导性项目(08kjd530001) 常州工学院校级项目(YN0907)~~
关键词 生物源甘油 催化化学转化 化学应用 石化原料替代品 biomass glycerol catalytic chemical conversion chemical application substitute for petrochemicalmaterials
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  • 1Karaosmanoglu F , Cgzoglu K B, Tiiter M, et al. Investigation of the Refining Step of Biodiesel Productio[J]. Energy Fuels, 1996 ,10( 4) :890-895. 被引量:1
  • 2Ganapati D Y, Payal A C, Devendra P T. Hydrogenolysis of Glycerol to 1, 2-Propanediol over Nano-fibrous Ag-OMS-2 Catalysts[J]. Ind Eng Chem Res ,2012 ,51: 1549-1562. 被引量:1
  • 3Ott L, Bicker, Payal A C, et al. Catalytic Dehydration of Glycerol in Sub- and Supercritical Water: A New Chemical Process for Acrolein Production[J]. Green Chem,2006,8(2) :214-220. 被引量:1
  • 4Zhou C H, BeltraminiJ N, Fana Y X, et al. Chemoselective Catalytic Conversion of Glycerol as a Biorenewable Source to Valuable Commodity Chemicals[J]. Chem Soc Rev,2008,37(3) :527-549. 被引量:1
  • 5Pagliaro M, Ciriminna R, Kimura H, et al. From Glycerol to Valued-added Products[J]. Angew Chem Int Ed, 2007,46: 4434-4440. 被引量:1
  • 6Ruppert AM, Weinberg K, Palkovits R. Hydrogenolysis Goes Bio , From Carbohydrates and Sugar Alcohols to Platform Chemicals[J]. Angew Chem Int Ed,2012,51:2564-2601. 被引量:1
  • 7冯建,袁茂林,陈华,李贤均.甘油催化氢解的研究与应用[J].化学进展,2007,19(5):651-658. 被引量:36
  • 8黄志威,崔芳,左建良,陈静,夏春谷.甘油催化氢解制备1,2-丙二醇催化剂研究进展[J].分子催化,2011,25(3):281-288. 被引量:2
  • 9Wu ZJ , Mao Y Z, Song M , et al. Cui Boehmite : A Highly Active Catalyst for Hydrogenolysis of Glycerol to 1 ,2-Propanediol[J]. Catal Commun,2013,32:52-57. 被引量:1
  • 10Kwak B K,Park D S, Yun Y S,et al. Preparation and Characterization of Nanocrystalline CuAl204 Spinel Catalysts by Sol?gel Method for the Hydrogenolysis of Glycerol[J]. Catal Commun,2012,24 :90-95. 被引量:1

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