摘要
The template method for preparing nanostructures entails the synthesis of the desired material within the pores of a nanoporous membrane. In this work, TiO2 nanotubules of the anatase form have been synthesized by sol-gel chemical method using porous anodic alumina as the template. Transmission electron microscopy（TEM）, scanning electron microscopy（SEM）, infrared spectroscopy（IR） and X-ray diffraction were used to investigate the structure and morphology of the TiO2 nanotubules. The results showed that the diameter and length of the obtained nanotubules were determined by the pore size and length of the PAA template. It was founded that through control of immersion time, both tubules and fibrils can be prepared; in addition, the wall thickness of the nanotubules can be varied at will. The result indicated that the sol particles absorbed preferably to the pore walls of the PAA membrane due to the fact that the pore walls were negatively charged and the TiO2 particles were positively charged.
The template method for preparing nanostructures entails the synthesis of the desired material within the pores of a nanoporous membrane. In this work, TiO_2 nanotubules of the anatase form have been synthesized by sol-gel chemical method using porous anodic alumina as the template. Transmission electron microscopy(TEM), scanning electron microscopy(SEM), infrared spectroscopy(IR) and X-ray diffraction were used to investigate the structure and morphology of the TiO_2 nanotubules. The results showed that the diameter and length of the obtained nanotubules were determined by the pore size and length of the PAA template. It was founded that through control of immersion time, both tubules and fibrils can be prepared; in addition, the wall thickness of the nanotubules can be varied at will. The result indicated that the sol particles absorbed preferably to the pore walls of the PAA membrane due to the fact that the pore walls were negatively charged and the TiO_2 particles were positively charged.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2001年第1期130-132,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金!(批准号 :6 9890 2 2 0 )资助
