摘要
本文通过3,6-二肼基-1,2,4,5-四嗪(DHT)分别与高氯酸和硝酸反应得到2种高氮含能离子盐,并通过X-射线单晶衍射技术对它们的结构进行了表征。(DHT)(NO3)2(1)属于单斜晶系,C2/c空间群,晶胞参数:a=1.300 0(6)nm,b=0.834 9(3)nm,c=1.018 7(5)nm,β=118.89(5)°,Z=4;(DHT)(ClO4)2(2)属于正交晶系,P21212空间群,晶胞参数:a=0.980 4(4)nm,b=1.074 7(4)nm,c=0.532 5(2)nm,Z=2。采用DSC和TG-DTG技术研究了这两种含能离子盐的热分解机理,并对这两种含能离子盐的非等温动力学、爆热及感度进行了测试分析。研究表明这两种含能离子盐在敏感型含能材料领域具有潜在的应用前景。
Two high-nitrogen energetic salts were prepared by reacting 3,6-dihydrazino-1,2,4,5-tetrazine （DHT） and perchloric acid or nitric acid aqueous solution. Their structures have been determined by using X-ray single crystal diffraction method. （DHT）（NO3）2 （1） belongs to monoclinic, C2/c space group, a=1.300 0 （6） nm, b= 0.834 9（3） nm, c=1.018 7（5） nm,β=118.89（5）°, Z=4; （DHT）（ClO4）2 （2） belongs to orthorhombic, P212,2 space group, a=0.980 4 （4） nm, b=1.074 7 （4） nm, c=0.532 5 （2） nm, Z=2. The thermal decomposition was investigated with DSC and TG-DTG measurement. The non-isothermal kinetic parameters of the first exothermic process were studied by applying Kissingers, Ozawa-Doyles and Starinks methods. The critical temperature of thermal explosion and sensitivity properties also have been fully investigated. We can come to the conclusion that the two salts have potential application in sensitive energetic material area. CCDC： 884111, 1; 884112, 2.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2013年第12期2587-2594,共8页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金项目(No.10776002)
爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03)
教育部新世纪优秀人才支持计划(No.NCET-09-0051)资助项目
关键词
晶体结构
含能离子盐
3
6-二肼基-1
2
4
5-四嗪
热分解
感度
crystal structure
energetic ionic salts
3,6-dihydrazino-l,2,4,5-tetrazine
thermal decomposition
sensitivity
