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A twin-axial[5]pseudorotaxane based on cucurbit[8]uril and a-cyclodextrin 被引量：6

A twin-axial[5]pseudorotaxane based on cucurbit[8]uril and a-cyclodextrin
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摘要 A twin-axial hetero[5]pseudorotaxane was constructed based on 1-hexyl-4,40-bipyridinium guest 1 and cucurbit[8]uril（CB[8]）and a-cyclodextrin（a-CD）.In its structure,CB[8]included two bipyridinium units to realize the twin-axial mode,and the hexyl chain was threaded into the cavity of a-CD.The[5]pseudorotaxane contains two types of macrocyclic hosts while the single axial and twin axial modes co-exist in its structure.The transformation of[5]pseudorotaxane could be realized by the addition of acid and 2,6-dihydroxynaphthalene（HN）. A twin-axial hetero[5]pseudorotaxane was constructed based on 1-hexyl-4,40-bipyridinium guest 1 and cucurbit[8]uril（CB[8]）and a-cyclodextrin（a-CD）.In its structure,CB[8]included two bipyridinium units to realize the twin-axial mode,and the hexyl chain was threaded into the cavity of a-CD.The[5]pseudorotaxane contains two types of macrocyclic hosts while the single axial and twin axial modes co-exist in its structure.The transformation of[5]pseudorotaxane could be realized by the addition of acid and 2,6-dihydroxynaphthalene（HN）.
作者 Li-Hua Wang Zhi-Jun Zhang Heng-Yi Zhang Hai-Lang Wu Yu Liu
机构地区 Department of Chemistry
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第11期949-952,共4页 中国化学快报（英文版）
基金 the National Basic Research Program of China (973 Program, No. 2011CB932500) the National Natural Science Foundation of China (Nos. 20932004 and 91227107) for fnancial support
关键词 Pseudorotaxane Cucurbituril Cyclodextrin Self-assembly Pseudorotaxane Cucurbituril Cyclodextrin Self-assembly
分类号 O621.3 [理学—有机化学]
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Chinese Chemical Letters
2013年 第11期

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