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高韧性苯并噁嗪的合成及其在层压板中的应用 被引量:2

Synthesis of benzoxazine with high toughness and its application in laminate
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摘要 以甲醛、二元胺及十二烷基酚为原料合成了1种新型苯并噁嗪树脂(FBZ),采用红外光谱、核磁氢谱对FBZ的结构进行了表征,通过示差扫描量热及热失重分析对其固化物(PFBZ)的热性能进行了研究,并首次将FBZ应用于层压板,研究了FBZ用量对层压板力学性能的影响。结果表明,PFBZ的玻璃化转变温度,5%热失重温度分别为135℃和339℃,800℃残炭率为50%,耐热性好;随着FBZ用量的增加,层压板的弯曲强度由560MPa上升至720 MPa,拉伸强度由355 MPa提高至469 MPa,韧性高。 The novel benzoxazine (FBZ)was synthesized using formaldehyde, diamine and dedocyl phenol as mate- rials. The structure of FBZ was characterized by FTIR and 1H - NMR. The thermal properties of FBZ cured product (PFBZ) was studied by DSC and TGA. The FBZ was applied in the laminate for the first time and the effect of FBZ amount on the mechanical properties of laminate was investigated. The result showed that the PFBZ had good heat resistance and its glass transition temperature, 5% weight loss temperature and char yield at 800℃ was 135 ℃, 339℃ and 50% , respectively. The flexural strength of FBZ was increased from 560 MPa to 720 MPa and tensile strength was incresed from 355 MPa to 469 MPa with the increasing of FBZ amount. The FBZ had high toughness.
出处 《热固性树脂》 CAS CSCD 北大核心 2013年第6期45-48,共4页 Thermosetting Resin
基金 国家863基金项目(2013AA030701)资助
关键词 高韧性 苯并噁嗪 层压板 弯曲强度 拉伸强度 high toughness benzoxazine laminate flexural strength tensile strength
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参考文献7

  • 1Ning Xin, Hatsuo lshida. Phenolic materials via ring - opening poly- merization: synthesis and characterization of bisphenol - A based benzoxazines and their polymers [ J ]. Journal of Polymer Science Part A Polym. Chem. ,1994,32(6) :1121 -1129. 被引量:1
  • 2Ishida H, Allen D J. Physical and mechanical characterization of near - zero shrinkage poly - benzoxazines [ J ]. J. Polym. Sci. , Part B: Polym. Phys., 1996,34(6): 1019-1030. 被引量:1
  • 3Frank Cheng - Yu Wang, Dettloff M L, Null M J. Qualitative and quantitative analysis of a thermoset polymer, poly(benzoxamine), by pyrolysis - gas chromatography [ J ]. Journal of ChromatographyA, 2000, 886(1/2) :217-224. 被引量:1
  • 4Hatsuo lshida, Daniel P, Sanders. Improved thermal and mechani- cal properties of polybenzoxazines based on alkyl - substituted aro- matic amines [ J ]. Journal of Polymer Science : Part B : Polymer Physics, 2000, 38(24): 3289-3301. 被引量:1
  • 5徐庆玉,王洛礼,李翔,范和平,刘应玖.新型苯并噁嗪树脂无卤覆铜板的研制[J].覆铜板资讯,2009(3):29-31. 被引量:3
  • 6刘锋,赵恩顺,马庆柯,唐安斌.含硼苯并噁嗪玻璃布层压板的研制[J].热固性树脂,2009,24(2):23-25. 被引量:6
  • 7Suzuki,Hironori.难燃性树脂组成物およびこの组成物を用いるプリブレグ,积屑板,プリント配线板:JP,2004197032[P].2004-07-15. 被引量:1

二级参考文献6

  • 1Hatsuo Ishida, Daniel P, Sanders. Improved thermal and mechanical properties of polybenzoxazines based on alkyl - substituted aromatic amines [ J ]. Journal of Polymer Science: Part B: Polymer Physies, 2000, 38:3289-3301. 被引量:1
  • 2Frank Cheng- Yu Wang, M L Dettloff, M J Null. Qualitative and quantitative analysis of a thermoset polymer, poly ( benzoxazine), by pyrolysis - gas chromatography [ J ]. Journal of Chromatography A, 2000, 886 : 217 - 224. 被引量:1
  • 3H J Kim. Z Brunovska, H lshida. Synthesis and lhennal characterization of polybenzoxazines based on acetylene - functional monomers [ J ]. Polymer, 1999.40 : 6565 - 6573. 被引量:1
  • 4Pauline M Barros, I Vate'ria P Yoshida, Marco A Schiavon. Boroneontaining puly( vinyl alcohol) as a ceramic precursor[ J ]. Journal of Non-Crystalline Solids. 2006, 352:3444 -3450. 被引量:1
  • 5C Mart'n, B J Hunt, J R Ebdon. Synthesis erosslinking and flame retardanee of polymers of boron-containing difunctional styrenic monomers [ J ]. Reactive & Funetional Polymers, 2006, 66 : 1047 - 1054. 被引量:1
  • 6凌鸿,顾宜,谢美丽.F级苯并噁嗪树脂基玻璃布层压板的研制[J].绝缘材料,2001,34(1):20-23. 被引量:14

共引文献7

同被引文献117

  • 1杨斌,闫红英,杨晓军.2.5D碳/酚醛模压复合材料的性能研究[J].纤维复合材料,2013,30(4). 被引量:4
  • 2Sebenik U, Krajnc M. Synthesis, curing kinetics, thermal and mechanical behavior of novel cardanol-based benzoxazines [J]. Polymer, 2015, 76 ( 2 ) : 203-212. 被引量:1
  • 3Liu C, Shen D, Sebasti 6 n R M, et al. Mechanistic studies on ring-opening polymerization of benzoxazines: A mechanistically based catalyst design [J]. Macromolecules, 2011, 44 ( 12 ) : 4616-4622. 被引量:1
  • 4Ishida H, Allen D J. Mechanical characterization of copolymers based on henzoxazine and epoxy [J]. Polymer, 1996, 37 ( 20 ) : 4487-4495. 被引量:1
  • 5Takeichi T, Kano T, Agag T. Synthesis and thermal cure of high molecular weight polybenzoxazine precursors and the properties of the thermosets [J]. Polymer, 2005, 46 ( 26 ) : 12172-12180. 被引量:1
  • 6Min Y, Huang S, Wang Y, et al. Sonoehemieal transformation of epoxy-amine thermoset into soluble and reusable polymers [J]. Maeromoleeules, 2015, 48 ( 2 ) : 316-322. 被引量:1
  • 7Arslan M, Kiskan B, Yagei Y. Benzoxazine-based thermosets with autonomous self-healing ability [J]. Maeromoleeules, 2015, 48 ( 5 ) : 1329-1334. 被引量:1
  • 8Goward G R, Sebastiani D, Schnell l, et al. Benzoxazine oligomers: Evidence for a helical structure from solid-state NMR spectroscopy and DFT-based dynamics and chemical shift calculations [J]. Journal of the American Chemical Society, 2003, 125 ( 19 ) : 5792-5800. 被引量:1
  • 9Park S J, Jin F L, Park J H, et al. Synthesis of a novel siloxane-eontaining diamine for increasing flexibility of epoxy resins [J]. Materials Science & Engineering A, 2005, 399 ( 1 ) : 377-381. 被引量:1
  • 10Yagei Y, Kiskan B, Ghosh N N. Recent advancement on polybenzoxazine-a newly developed high performance thermoset [J]. Journal of Polymer Science Part A: Polymer Chemistry, 2009, 47 ( 21 ) : 5565-5576. 被引量:1

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