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Reduced graphene oxide with a highly restored π-conjugated structure for inkjet printing and its use in all-carbon transistors 被引量:4

Reduced graphene oxide with a highly restored π-conjugated structure for inkjet printing and its use in all-carbon transistors
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摘要 An inkjet-printed graphene film is of great importance for next-generation flexible, low cost and high performance electronic devices. However, due to the limitation of the inkjet printing process, the electrical conductivity of inkjet-printed graphene films is limited to N10 S'cm-1, and achieving a high conductivity of the printed graphene films remains a big challenge. Here, we develop a "weak oxidation- vigorous exfoliation" strategy to tailor graphene oxide (GO) for meeting all the requirements of highly conductive inkjet-printed graphene films, including a more intact carbon plane and suitable size. The -conjugated structure of the resulting graphene has been restored to a high degree, and its printed films show an ultrahigh conductivity of -420 S-cm-I, which is tens of times higher than previously reported results, suggesting that, aside from developing a highly efficient reduction method, tuning the GO structure could be an alternative way to produce high quality graphene sheets. Using inkjet-printed graphene patterns as source/drain/gate electrodes, and semiconducting single-walled carbon nanotubes (SWCNTs) as channels, we fabricated an all-carbon field effect transistor which shows excellent performance (an on/off ratio of -104 and a mobility of -8 cm2"V-l's-1) compared to previously reported CNT-based transistors, promising the use of nanocarbon materials, graphene and SWCNTs in printed electronics, especially where high performance and flexibility are needed. 一部打印 inkjet 的 graphene 电影为下一代的灵活、低费用和高效是很重要的电子设备。由于打印过程的 inkjet 的限制,然而,打印 inkjet 的 graphene 电影的电的传导性被限制到 10
出处 《Nano Research》 SCIE EI CAS CSCD 2013年第11期842-852,共11页 纳米研究(英文版)
关键词 inkjet printing graphene oxide high conductivity field effect transistor 单壁碳纳米管 场效应晶体管 氧化石墨 喷墨印刷 共轭结构 氧化物 SWCNTs 印刷薄膜
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