摘要
以丙烯酰胺(AM)和2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为单体,采用氧化还原引发体系在水溶液中合成二元共聚物。结果表明:采用(NH4)2S2O8/NaHSO2CH2OH引发剂,AMPS与AM单体总质量分数25%,二者质量比3∶7,引发剂占单体总量的质量分数0.09%,其中氧化剂与还原剂质量比4∶1,pH=6,反应温度20℃时,AM/AMPS共聚物表观黏度最高,与工业部分水解聚丙烯酰胺(HPAM,3 500万)相比具有更好的耐温抗盐性能。
The copolymer of acrylamide （AM）/2-acrylamido-2-methyl propane sulfonic acid （AMPS） is synthesized using oxida- tion-reduction initiation system by aqueous solution polymerization. The results show that the copolymer has the highest apparent viscos- ity when the initiatior is （ NH4 ）2 S2O8/NaHSO2 CH2 OH, the concentration of monomer is 25% , mass radio of AMPS to AM equals to 7 ： 3, the concentration of initiator in monomer is 0. 09% , mass radio of （ NH4 ） 2 $20s to NaHSO2 CH2 OH is 4 ： 1, pH value is 6, the reaction temperature is 20 ℃. In comparison with hydrolyzed potyaeryamide （ HPAM ,3.5~107 ） , the copolymer has better performance of heat-resistant and salt-toleration.
出处
《化学工业与工程技术》
CAS
2013年第5期49-52,共4页
Journal of Chemical Industry & Engineering
关键词
丙烯酰胺
2-丙烯酰胺基-2-甲基丙磺酸
共聚物
耐温抗盐
Acrylamide
2-Acrylamido-2-methyl propane sulfonic acid
Copolymer
Heat-resistant and salt-tolerant
