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{[Ag(ATO)_(2)]ClO_(4)}_(n)的合成、结构表征和热分解机理 被引量:4

Synthesis,Structural Characterization and Thermal Decomposition Mechanism of {[Ag(ATO)_(2)]ClO_(4)}_(n)
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摘要 A new supermolecule coordination compound of perchlorate di(4- amino- 1,2,4- tri azole- 5- one)silver(I) was synthesized. It was characterized by element analysis, FT- IR, X- ray crystallogram and single crystal diffraction. The titled complex was also studied by means of TG- DTG and DSC under conditions of linear temperature increase. The thermal decomposition remainders were determined by infrared spectroscopic analysis. Thermal decomposition mechanism of the title coordination compound was suggested. A new supermolecule coordination compound of perchlorate di(4- amino- 1,2,4- tri azole- 5- one)silver(I) was synthesized. It was characterized by element analysis, FT- IR, X- ray crystallogram and single crystal diffraction. The titled complex was also studied by means of TG- DTG and DSC under conditions of linear temperature increase. The thermal decomposition remainders were determined by infrared spectroscopic analysis. Thermal decomposition mechanism of the title coordination compound was suggested.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2000年第12期1110-1114,共5页 Acta Physico-Chimica Sinica
关键词 4-氨基-1 2 4-三唑-5-酮(ATO) 银配合物 结构表征 热分解机理 Silver complex Structural characterization 4-amino-1 2 4-triazol-5-one(ATO) Thermal decomposition mechanisms
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