期刊文献+

乙醇裂解协同制备氢气和碳纳米管 被引量:1

The decomposition of ethanol to produce hydrogen and multi-wall carbon nanotubes
下载PDF
导出
摘要 以乙醇为碳源,采用浸渍法制备的担载量为Fe(5%)/C催化剂,利用化学气相沉积法协同制备碳纳米管和氢气,分析了裂解温度(500~800℃)对于产生氢气产率和碳纳米管品质的影响.对于Fe(5%)/C催化裂解乙醇,最佳的反应温度为600 ℃,碳管的品质较好,氢气的产率最高为75%,生成的碳管为多壁碳纳米管. Ethanol as carbon source,the effects of reaction temperature on the yield of hydrogen and the quality of carbon nanotubes (CNTs) over the Fe(5%)/C from the decomposition were investigated systematically.Ethanol decomposition was studied over Fe (5%)/C to produce hydrogen and carbon nanotubes by chemical vapor deposition at the temperature of 500 ~ 800 ℃.The optimal reaction temperature was 600 ℃ for hydrogen and the growth of MWCNT from ethanol decomposition over the Fe(5%)/C,H2 yield was 75 %,the produced carbon nanotubes was multi-walled carbon nanotubes (MWCNTs) (being of relatively higher and low defect).
作者 刁金香 王惠
出处 《应用化工》 CAS CSCD 2013年第9期1580-1582,共3页 Applied Chemical Industry
基金 国家自然科学基金国际合作研究项目(21061130551) 教育部博士点基金(20096101110002)
关键词 乙醇裂解 氢气 多壁碳纳米管 FE C催化剂 ethanol decomposition hydrogen multi-wall carbon nanotubes Fe/C catalyst
  • 相关文献

参考文献7

  • 1Ebbesen T W, Ajayan P M. Large-scale synthesis of car- bon nanotubes [ J]. Nature, 1992,358:220-222. 被引量:1
  • 2Guo T, Nikolaea P, Colber D T, et al. Catalytic growth of single-walled nanotubes by laser vaporization [ J ]. Chem Phys Lett, 1995,243 : 49-54. 被引量:1
  • 3Yang W C, Yang T Y, Yew T R, et al. Growth of self- aligned carbon nanotube for use as a field-effect transistorusing cobalt silicide as a catalyst [ J ]. Carbon, 2007,45 (8) :1679-1685. 被引量:1
  • 4Cabero M P, Ramosi I R, Ruiz A G. Characterization of carbon nanotubes and carbon nanofiber prepared by cata- lytic decomposition of acetylene in a fluidized bed reactor [ J ]. J Catal, 2003 ( 215 ) : 305-316. 被引量:1
  • 5Rao A M,Richter E, Bandow S J,et al. Diameter-selective Raman scattering from vibrational modes in carbon nano- tubes [ J ]. Science, 1997,275 : 187-191. 被引量:1
  • 6Giraudet S, Pre P, Tezel H, et al. Estimation of adsorption energies using physical characteristics of activated carbons and VOC' s molecular properties [ J ]. Carbon, 2006,44 (10) :1873-1883. 被引量:1
  • 7Sinnott S B, Anderws R, Qian D, et al. Model of carbon nanotube growth through chemical vapor deposition [ J ]. Chem Phys Lett, 1999,315:25-30. 被引量:1

同被引文献1

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部