摘要
以乙醇为碳源,采用浸渍法制备的担载量为Fe(5%)/C催化剂,利用化学气相沉积法协同制备碳纳米管和氢气,分析了裂解温度(500~800℃)对于产生氢气产率和碳纳米管品质的影响.对于Fe(5%)/C催化裂解乙醇,最佳的反应温度为600 ℃,碳管的品质较好,氢气的产率最高为75%,生成的碳管为多壁碳纳米管.
Ethanol as carbon source,the effects of reaction temperature on the yield of hydrogen and the quality of carbon nanotubes (CNTs) over the Fe(5%)/C from the decomposition were investigated systematically.Ethanol decomposition was studied over Fe (5%)/C to produce hydrogen and carbon nanotubes by chemical vapor deposition at the temperature of 500 ~ 800 ℃.The optimal reaction temperature was 600 ℃ for hydrogen and the growth of MWCNT from ethanol decomposition over the Fe(5%)/C,H2 yield was 75 %,the produced carbon nanotubes was multi-walled carbon nanotubes (MWCNTs) (being of relatively higher and low defect).
出处
《应用化工》
CAS
CSCD
2013年第9期1580-1582,共3页
Applied Chemical Industry
基金
国家自然科学基金国际合作研究项目(21061130551)
教育部博士点基金(20096101110002)
关键词
乙醇裂解
氢气
多壁碳纳米管
FE
C催化剂
ethanol decomposition
hydrogen
multi-wall carbon nanotubes
Fe/C catalyst