摘要
介绍了一种采用无毒廉价的前驱物制备Fe3O4@SiO2-Ag磁性纳米微球的快捷方法,制备的Fe3O4@SiO2-Ag纳米微球在NaBH4存在下可以催化还原染料污染物.实验结果表明,Fe3O4@SiO2-Ag磁性纳米粒子保持了Ag纳米粒子和Fe3O4纳米粒子的双重优点,不仅对染料罗丹明B和曙红Y具有良好的催化还原效率,而且可以在外加磁场作用下从溶液中快速有效的分离.催化还原反应速率与反应温度及Fe3O4@SiO2-Ag催化剂用量有关,反应体系中表面活性剂和无机盐(Na2SO4)的存在也会影响催化剂的催化活性.该Fe3O4@SiO2-Ag磁性纳米粒子在工业染料污染物处理方面具有应用前景.
A simple electroless plating method using non-toxic, cost-effective precursors to fabricate Fe3O4@SiO2-Ag nanospheres for catalytic reduction of dye pollutants is developed. Incorporating the individual advantages of Ag and Fe3O4 nanoparticles, the Fe3O4@SiO2-Ag nanospheres exhibit enhanced catalytic reduction efficiency for rhodamine B and eosin Y compared with those of pure Ag or Fe3O4 nanoparticles, and can also be rapidly separated from aqueous solution using a magnet. The catalytic reaction rate is strongly dependent on both reaction temperature and Fe3O4@SiO2-Ag dosage. The presence of surfactants and inorganic salt （Na2SO4） influences the catalytic activity of the Fe3O4@SiO2-Ag nanospheres. Fe3O4@SiO2-Ag nanospheres show great promise for the treatment of industrial dye pollutants.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2013年第7期1378-1385,共8页
基金
supported by the National Natural Science Foundation of China(J1103307)
the Natural Science Foundation of Gansu Province in China(3ZS041‐A25‐009)~~
