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金属碳笼的研究进展

The recent progress in the studies of met-cars
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摘要 金属碳笼是继笼状结构C60之后发现的又一个"明星团簇".人们对它的几何拓扑结构和电子结构特性进行了广泛研究.概述了金属碳笼的稳态结构、电子结构和光谱学特性以及金属碳笼生长模式的研究成果.最后介绍了金属碳笼作为储氢材料的最新研究进展,并对其应用前景进行了展望. Metallo-Carbohedrenes are a group of clusters which have attracted much attention following C60. Their geometry and ground electronic states have been studied extensively. In,this paper the recent progress in the studies of their lowest-energy structure, electronic structure, absorption spectrum and growth mechanism are summarized. The latest developments of using met-cars as hydrogen storage material are introduced and the prospects of this field are discussed.
出处 《西南民族大学学报(自然科学版)》 CAS 2013年第4期593-598,共6页 Journal of Southwest Minzu University(Natural Science Edition)
基金 河北省高等学校科学技术研究重点项目(批准号:ZH2011101) Met-Cars的结构与磁性研究(20110401)
关键词 金属碳笼 稳态结构 电子结构 光谱学特性 生长机理 Metallo-Carbohedrenes geometric structure electronic state absorption spectrum growth mechanism
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参考文献23

  • 1GUO B C,KERNS K P,CASTLEMAN A W.Ti8C12+-Metallo-Carbohedrenes:A new class of molecular clusters[J].Science,1992,255(5050):1411-1413. 被引量:1
  • 2GUO B C,WEI S,PURNELL J,et al.Metallo-Carbohedrenes[Ti8C12+(M=V,Zr,Hf and Ti)] A class of stable molecular clusterions[J].Science,1992,256(5056):515-516. 被引量:1
  • 3WEI S,GUO B C,PURNELL J,et al.Metallo-Carbohedrenes as a class of stable neutral clusters:Formation mechanism ofTi8C12(M=Ti and V)[J].J Phys Chem,1992,96(11):4166-4168. 被引量:1
  • 4GUO B C,WEI S,CHEN Z,et al.Generation of metal-carbon and metal-nitrogen clusters with a laser induced plasma technique[J].JChem Phys,1992,97(7):5243-5245. 被引量:1
  • 5DANCE I.Geometric and electronic structures of[Ti8C12] :analogies with C60[J].J Chem Soc,Chem Commun,1992,24:1779-1780. 被引量:1
  • 6DANCE I.Ti8C12:Barrierless Transformation of the ThIsomer to the TdIsomer[J].J Am Chem Soc,1996,118(26):6309-6310. 被引量:1
  • 7CHEN H,FEYEREISEN M,LONG X P.Stability,bonding,and geometric structure of Ti8C12,Ti8N12,V8C12,and Zr8C12[J].Phy Revlett,1993,71(11):1732-1736. 被引量:1
  • 8ROHMER M M,BENARD M,HENRIET C,et al.Ti8C12:a polytopal molecule with 36 Ti-C bonds[J].J Chem Soc,Chem Commun,1993,15:1182-1185. 被引量:1
  • 9ROHMER M M,BENARD M,BO C,et al.Ab initio SCF and CI investigations on titanium-carbon clusters:metallo-carbohedrenesTi8C12and Fcc crystallites Ti14C13[J].J Am Chem Soc,1995,117(2):508-517. 被引量:1
  • 10LOU L,NORDLANDER P.An endohedral metallocarbohedrene C@Ti8C12[J].Chem Phys Lett,1994,224(5-6):439-444. 被引量:1

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