摘要
利用水热技术,以3,4,5,6-四氟邻苯二甲酸、1,10-邻菲罗啉衍生物、Pb(NO3)2.6H2O为原料合成了铅(Ⅱ)配合物C52H26F8N8O6Pb,并通过元素分析和X射线单晶衍射对其结构进行了表征.该晶体属于单斜晶系,P21/n空间群,a=10.573 5(4),b=16.748 5(5),c=24.649 5(6),β=96.181(3)°,V=4 339.8(2)3,Z=4.结构分析表明该配合物为零维结构,且通过氢键及π-π相互作用使之形成一维链状结构.
A new complex C52H26O6N8F8Pb based on 3,4,5,6-Tetrafluoro-phthalic acid,1,10-phenanthroline and its derivatives,Pb（NO3） 2.6H2O has been hydrothermally synthesized and characterized by elemental analysis and single-crystal X-ray diffraction.The title compound crystallizes is in monoclinic space group P21/ n with a = 10.573 5（4）,b = 16.748 5（5）,c = 24.649 5（6）,β = 96.181（3） °,V = 4 339.8（2）3,Z =4.Structure analysis shows that the title compound is zero-dimensional structure,and the neighboring units are further linked into a one-dimensional chain structure by hydrogen bonds and π-π interactions.
出处
《吉林师范大学学报（自然科学版）》
2013年第3期36-39,共4页
Journal of Jilin Normal University:Natural Science Edition
基金
教育部新世纪优秀人才项目(NCET-10-0176)
