摘要
以1-甲酰基-2-甲氧基薁-3-甲酸甲酯为反应底物,通过与邻苯二胺缩合、烷基化、脱羧等过程,成功地制备了新型薁并[1,2-f]苯并[1,4]二氮卓类衍生物.反应收率良好、操作简单、条件温和.产物结构通过红外光谱、核磁共振谱、质谱及元素分析证实.
Azuleno[1,2-f][1,4]benzodiazepine derivatives were synthesized by the three steps（condensation,alkylation and decarboxylation） of ethyl 1-formyl-2-methoxyazulene-3-carboxylate with o-phenylenediamine.This method provides several advantages such as good yield and simple work-up procedure.All the products were fully characterized by 1 H NMR,IR,MS spectra and elemental analyses.
出处
《渤海大学学报（自然科学版）》
CAS
2013年第2期161-165,共5页
Journal of Bohai University:Natural Science Edition
基金
辽宁省科技厅项目(No:2011220022)
