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High-strength composite yarns derived from oxygen plasma modified super-aligned carbon nanotube arrays 被引量:1

High-strength composite yarns derived from oxygen plasma modified super-aligned carbon nanotube arrays
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摘要 Spinning carbon nanotube (CNT) yarns from super-aligned carbon nanotube (SACNT) arrays is a promising approach to fabricate high-strength fibers. However the reported tensile strengths of the as-prepared fibers are far below that of an individual CNT. It is therefore still a challenge to improve their mechanical strengths. Here we report that the tensile strengths and Young's moduli can be further improved to 2.2 GPa and 200 GPa respectively, if we first treat the SACNT array with oxygen plasma by using a reactive ion etching (RIE) facility, then dry spin yarns from it and make composite fibers with polyvinyl alcohol. According to the experimental results obtained using scanning electron microscopy (SEM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS), the improvement is attributed to the oxygen RIE process, as it can create functional groups on the outer walls of CNTs and thus improve the interaction between the CNTs and the polymer molecules.
出处 《Nano Research》 SCIE EI CAS CSCD 2013年第3期208-215,共8页 纳米研究(英文版)
关键词 carbon nanotube yarns super-aligned carbonnanotube array 02 plasma mechanical properties 碳纳米管阵列 氧等离子体处理 高强度纤维 等离子体改性 复合纱线 X射线光电子能谱 拉伸强度 电子显微镜
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