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一种2,5-二羟基对苯二甲酸与Mn(Ⅱ)配合物的合成、晶体结构及表征 被引量:4

Synthesis,Crystal and IR of the 2,5-dihydroxyterephthalic Acid Mn(Ⅱ) Coordination Complexes
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摘要 本文合成一种新的2,5-二羟基对苯二甲酸(2,5-dihydroxyterephthalic acid)(DHTA)、1,10-邻菲罗啉(1,10-Phenanthroline monohydrate)(phen)和Mn(Ⅱ)配位聚合物,并采用单晶衍射、红外光谱表征. A novel 2,5-dihydroxyterephthalic acid Mn ( Ⅱ) Coordination Complexes has been synthesized and Characterized by X-ray diffraction and IR. The title compound crystallizes in triclinic, P-1, a = 10.676 (4) A, b = 11.917(4) A,c=12.683(4) А,a= 66.446(5)°,β=76.680(5)°,γ= 78.341(5)°,Ⅴ=1428.3(8) А^3,Dc = 1. 628 g/cm^3 ,Z =2 ,GOOF = 0.977 ,R =0.0544,wR =0. 1354.
出处 《吉林师范大学学报(自然科学版)》 2013年第2期15-17,25,共4页 Journal of Jilin Normal University:Natural Science Edition
基金 吉林省科技发展计划项目(20080406)
关键词 配合物 晶体 2 5-二羟基对苯二甲酸 coordination compound crystal 2,5-dihydroxyterephthalic acid
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