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CaSO_4·(1/2)H_2O粉末中结晶水与吸附水1~H的Goldman-Shen实验

~1H GOLDMAN-SHEN EXPERIMENT ON CRYSTALLINE AND ADSORBED WATERS IN CaSO_4 ·(1/2) H_2O POWDER
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摘要 本文利用Goldman-Shen脉冲序列测量了CaSO_4·(1/2)H_2O样品中结晶水与吸附水~1H的交叉弛豫时间为55.1ms。在实验中,发现剩余窄线的磁化矢量随时间的衰减有三个过程。本文对此现象作了一些分析讨论。 ~1H cross relaxation time between crystalline and adsorbed waters in CaSO_4 1/2 H_2O powder was found to be 55.1 ms by use of the Goldman-Shen pulse sequence. In experiment, it was discovered that the narrow component of the ~1H spectrum line decays with three time constants. The present paper gives some explanations for the experimental results.
出处 《波谱学杂志》 CAS CSCD 1991年第1期107-112,共6页 Chinese Journal of Magnetic Resonance
关键词 CASO4 结晶水 吸附水 NMR Nuclear magnetic resonance, Solid sample, Cross relaxation.
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