摘要
Composite polymer electrolytes based on poly（ethylene oxide）-polysiloxane/l-butyl-3-methylimida- zolium bis（trifluoromethanesulfonyl）imide/organomontmorillonite （PEO-PDMS/IL/OMMT） were pre- pared and characterized. Addition of both an ionic liquid and OMMT to the polymer base of PEO-PDMS resulted in an increase in ionic conductivity. At room temperature, the ionic conductivity of sample PPB 100-OMMT4 was 2.19 × 10-3 S/cm. The composite polymer electrolyte also exhibited high thermal and electrochemical stability and may potentially be applied in lithium batteries.
Composite polymer electrolytes based on poly（ethylene oxide）-polysiloxane/l-butyl-3-methylimida- zolium bis（trifluoromethanesulfonyl）imide/organomontmorillonite （PEO-PDMS/IL/OMMT） were pre- pared and characterized. Addition of both an ionic liquid and OMMT to the polymer base of PEO-PDMS resulted in an increase in ionic conductivity. At room temperature, the ionic conductivity of sample PPB 100-OMMT4 was 2.19 × 10-3 S/cm. The composite polymer electrolyte also exhibited high thermal and electrochemical stability and may potentially be applied in lithium batteries.
基金
financially supported by the National 863 Program(No.2011AA11A235)
the National Key Program for Basic Research of China(No.2009CB220100)
Basic Research Fund of Beijing Institute of Technology(No.3100012211111 )
