摘要
在Tang和Chan所给出的氢原子的2-l极动态极化率的微分表达式的基础上,进一步导出了氢原子电多极动态极化率的解析表达式,从而完全解决了氢原子动态极化率的计算问题.应用此解析表达式,首次计算了氢原子H(2s)-H(2s)-H(2s)体系的三体相互作用系数.
An analytic expression for the 2l-pole dynamic polarizability of hydrogen atom in an arbitrary state is derived from a differential expression obtained by Tang and Chan,and the problem of calculating the 2l-pole dynamic polarizability of hydrogen is solved.As an application,new three-body van der Waals dispersion coefficients for the H（2s）-H（2s）-H（2s） system are calculated from integrals of products of the dynamic polarizabilities of the interacting atoms.
出处
《安徽师范大学学报（自然科学版）》
CAS
北大核心
2012年第5期429-434,共6页
Journal of Anhui Normal University(Natural Science)
基金
Supported by Scientific Research Foundation of the State Human Resource Ministry for Returned Chinese Scholars under Grant No.2005LXAH06
Natural Science Foundation of Anhui Province under Grant Nos.11040606M15
关键词
氢原子
动态极化率
解析表达式
相互作用系数
hydrogen atom
dynamic polarizability
analytic expression
dispersion coefficient
